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Information on EC 4.4.1.4 - alliin lyase
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4.4.1.4 alliin lyaseIUBMB Comments
A pyridoxal-phosphate protein.
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Word Map
- 4.4.1.4
- garlic
- allium
- allicin
- sativum
- onion
- thiosulfinates
-
crush
- clove
-
organosulfur
-
s-alkenyl-l-cysteine
- alliaceae
- leek
- s-allyl-l-cysteine
-
lachrymatory
- medicine
-
acsos
-
s-allyl
- synthesis
- nutrition
- drug development
- biotechnology
- analysis
- pharmacology
The expected taxonomic range for this enzyme is: Eukaryota, Bacteria
Synonyms
alliinase, alliin lyase, cysteine sulfoxide lyase, allinase, alliin-lyase, l-cysteine sulfoxide lyase, 
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SYNONYM 
ORGANISM
UNIPROT
COMMENTARY 
LITERATURE
alkylcysteine sulfoxide lyase
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-
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alliin-lyase
alliinase
allinase
C-S lyase
cys sulfoxide lyase
cysteine sulfoxide lyase
Cysteine sulphoxide lyase
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-
-
-
L-cysteine sulfoxide lyase
-
-
-
-
lyase, alliin
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-
-
-
P-19486 alliinase
S-alkyl(en)yl-L-cysteine lyase
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-
-
-
S-alkylcysteine sulfoxide lyase
-
-
-
-
additional information
the enzyme belongs to the fold-type I family of pyridoxal-5'-phosphate-dependent enzymes
alliinase
-
-
-
-
alliinase
-
-
cysteine sulfoxide lyase
-
-
-
-
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REACTION
REACTION DIAGRAM
COMMENTARY
ORGANISM
UNIPROT
LITERATURE
an S-alkyl-L-cysteine S-oxide = an alkyl sulfenate + 2-aminoacrylate
-
-
-
-
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REACTION TYPE
ORGANISM
UNIPROT
COMMENTARY
LITERATURE
elimination
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-
of RSH, C-S bond cleavage
-
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PATHWAY SOURCE
PATHWAYS
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, , , , ,
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SYSTEMATIC NAME
IUBMB Comments
S-alkyl-L-cysteine S-oxide alkyl-sulfenate-lyase (2-aminoacrylate-forming)
A pyridoxal-phosphate protein.
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CAS REGISTRY NUMBER
COMMENTARY
9031-77-0
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SUBSTRATE
PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
(+)-(S)-allyl-L-cysteine sulfoxide
2-propenyl 2-propenethiosulfinate + pyruvate + NH3
-
-
i.e. allicin
-
?
(+)-propiin + H2O
propane-1-sulfenic acid + pyruvate + NH3
-
-
-
?
(+-)-propiin + H2O
propane-1-sulfenic acid + pyruvate + NH3
-
-
-
?
(2R)-2-amino-3-(1-phenylethylsulfinyl)propanoic acid
(1-phenylethyl)sulfanol + pyruvate + NH4+
-
-
The sulfenic acid condenses with loss of water to form thiosulfinates. The alpha-aminoacrylic acid formed initially subsequently breaks down into pyruvate and ammonia
-
?
(2R)-2-amino-3-(2-methylbenzylsulfinyl)propanoic acid
(2-methylbenzyl)sulfanol + pyruvate + NH4+
-
-
The sulfenic acid condenses with loss of water to form thiosulfinates. The alpha-aminoacrylic acid formed initially subsequently breaks down into pyruvate and ammonia
-
?
(2R)-2-amino-3-(4-chlorobenzylsulfinyl)propanoic acid
(4-chlorobenzyl)sulfanol + pyruvate + NH4+
-
-
The sulfenic acid condenses with loss of water to form thiosulfinates. The alpha-aminoacrylic acid formed initially subsequently breaks down into pyruvate and ammonia
-
?
(2R)-2-amino-3-(4-methylbenzylsulfinyl)propanoic acid
(4-methylbenzyl)sulfanol + pyruvate + NH4+
-
-
The sulfenic acid condenses with loss of water to form thiosulfinates. The alpha-aminoacrylic acid formed initially subsequently breaks down into pyruvate and ammonia
-
?
(2R)-2-amino-3-(ethylsulfinyl)propanoic acid
(2R)-2-amino-3-(ethylsulfinyl)propanoic acid + pyruvate + NH4+
-
-
The sulfenic acid condenses with loss of water to form thiosulfinates. The alpha-aminoacrylic acid formed initially subsequently breaks down into pyruvate and ammonia
-
?
(2R)-2-amino-3-(phenethylsulfinyl)propanoic acid
phenethylsulfanol + pyruvate + NH4+
-
-
The sulfenic acid condenses with loss of water to form thiosulfinates. The alpha-aminoacrylic acid formed initially subsequently breaks down into pyruvate and ammonia
-
?
(2R)-2-amino-3-(phenylsulfinyl)propanoic acid
phenylsulfanol + pyruvate + NH4+
-
-
The sulfenic acid condenses with loss of water to form thiosulfinates. The alpha-aminoacrylic acid formed initially subsequently breaks down into pyruvate and ammonia
-
?
(R)-S-(2-pyridyl)cysteine N-oxide
2-sulfanylpyridine N-oxide + 2-aminoacrylate
-
-
2-sulfanylpyridine N-oxide can spontaneously rearrange into tautomeric and more stable N-hydroxypyridine-(1H)-thione, which can be transformed to 2-(methyldithio)pyridine N-oxide, 2-[(methylthio)methyldithio]pyridine N-oxide, di(2-pyridyl) disulfide N-oxide, and di(2-pyridyl) disulfide N,N'-dioxide
-
?
2-hydroxyethiin
(2-hydroxyethyl)sulfanol + pyruvate + NH4+
-
-
The sulfenic acid condenses with loss of water to form thiosulfinates. The alpha-aminoacrylic acid formed initially subsequently breaks down into pyruvate and ammonia
-
?
beta-chloro-L-Ala
?
-
95% of the activity with desglutamyl-lentinic acid
-
-
?
isoalliin
? + pyruvate + NH4+
-
-
The sulfenic acid condenses with loss of water to form thiosulfinates. The alpha-aminoacrylic acid formed initially subsequently breaks down into pyruvate and ammonia
-
?
L-(+)-S-(2-pyridyl)-cysteine sulfoxide + H2O
?
-
the amount of this cysteine sulfoxide, related to the fresh weight of bulbs, is between 0.13 and 0.44%
-
-
?
L-Cys sulfinic acid
?
-
0.5% of the activity with desglutamyl-lentinic acid
-
-
?
L-cystine
pyruvate + NH4+ + S2- + L-cysteine
-
cystine lyase activity of the enzyme alliinase
-
-
?
propiin
propylsulfanol + pyruvate + NH4+
-
-
The sulfenic acid condenses with loss of water to form thiosulfinates. The alpha-aminoacrylic acid formed initially subsequently breaks down into pyruvate and ammonia
-
?
S-(+)-allyl-L-cysteine sulfoxide + H2O
allyl 2-propenethiosulphinate
-
-
-
-
?
S-(methylthiomethyl)cysteine 4-oxide
(methylthio)methane-sulfenic acid + 2-aminoacrylate
-
i.e. marasmin
-
-
?
S-benzyl-L-cysteine sulfoxide
phenylmethanesulfenic acid + pyruvate + NH3
-
-
-
-
?
S-butyl-L-cysteine + H2O
butanethiol + NH3 + 2-oxopropanoate
-
-
-
?
S-ethyl-cysteine sulfoxide
diethyldisulfide-S-monoxide + pyruvate + NH4+
-
-
-
-
?
S-ethyl-L-cysteine + H2O
ethanethiol + NH3 + 2-oxopropanoate
-
-
-
?
S-methyl-cysteine sulfoxide
dimethyldisulfide-S-monoxide + pyruvate + NH4+
-
-
-
-
?
S-methyl-L-Cys sulfone
?
-
6% of the activity with desglutamyl-lentinic acid
-
-
?
S-methyl-L-cysteine + H2O
methanethiol + NH3 + 2-oxopropanoate
-
-
-
?
S-propyl-cysteine sulfoxide
dipropyldisulfide-S-monoxide + pyruvate + NH4+
-
-
-
-
?
S-propyl-L-cysteine + H2O
propanethiol + NH3 + 2-oxopropanoate
-
-
-
?
(+)-alliin
allicin + pyruvic acid + NH3
-
isolated from garlic and synthetic substrate (S)-allyl-L-cysteine sulfoxide
i.e. 2-propenyl 2-propenethiosulfinate
-
?
(+)-alliin
allicin + pyruvic acid + NH3
-
i.e. (+)-S-allyl-L-cysteine sulfoxide, low activity, the enzyme is more selectively for (-)-alliin than for (+)-alliin, a naturally occurring substrate for plant alliinase
-
-
?
(+)-S-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
-
-
-
?
(+)-S-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
-
-
-
?
(+)-S-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
-
-
-
?
(+)-S-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
-
-
-
?
(+)-S-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
-
-
-
?
(+)-S-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
-
-
-
?
(+)-S-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
-
-
-
?
(+)-S-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
-
-
-
?
(+)-S-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
-
-
-
?
(+)-S-propyl-L-cysteine sulfoxide
propane-1-sulfenic acid + pyruvate + NH3
-
-
-
-
?
(+)-S-propyl-L-cysteine sulfoxide
propane-1-sulfenic acid + pyruvate + NH3
-
-
-
-
?
(+)-S-propyl-L-cysteine sulfoxide
propane-1-sulfenic acid + pyruvate + NH3
-
-
-
-
?
(+)-S-propyl-L-cysteine sulfoxide
propane-1-sulfenic acid + pyruvate + NH3
-
-
-
-
?
(+)-S-propyl-L-cysteine sulfoxide
propane-1-sulfenic acid + pyruvate + NH3
-
-
-
-
?
(+/-)-(1-methyl)-L-cysteine sulfoxide
methanesulfenic acid + pyruvate + NH3
-
about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(1-methyl)-L-cysteine sulfoxide
methanesulfenic acid + pyruvate + NH3
-
about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(1-methyl)-L-cysteine sulfoxide
methanesulfenic acid + pyruvate + NH3
-
about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(1-methyl)-L-cysteine sulfoxide
methanesulfenic acid + pyruvate + NH3
-
about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(1-methyl)-L-cysteine sulfoxide
methanesulfenic acid + pyruvate + NH3
-
about 35% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(1-methyl)-L-cysteine sulfoxide
methanesulfenic acid + pyruvate + NH3
-
about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(1-methyl)-L-cysteine sulfoxide
methanesulfenic acid + pyruvate + NH3
-
about 35% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(1-methyl)-L-cysteine sulfoxide
methanesulfenic acid + pyruvate + NH3
-
about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(1-methyl)-L-cysteine sulfoxide
methanesulfenic acid + pyruvate + NH3
-
about 45% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(butyl)-L-cysteine sulfoxide
butane-1-sulfenic acid + pyruvate + NH3
-
8% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(butyl)-L-cysteine sulfoxide
butane-1-sulfenic acid + pyruvate + NH3
-
7% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(butyl)-L-cysteine sulfoxide
butane-1-sulfenic acid + pyruvate + NH3
-
about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(butyl)-L-cysteine sulfoxide
butane-1-sulfenic acid + pyruvate + NH3
-
6.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(butyl)-L-cysteine sulfoxide
butane-1-sulfenic acid + pyruvate + NH3
-
about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(butyl)-L-cysteine sulfoxide
butane-1-sulfenic acid + pyruvate + NH3
-
6.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(butyl)-L-cysteine sulfoxide
butane-1-sulfenic acid + pyruvate + NH3
-
about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(butyl)-L-cysteine sulfoxide
butane-1-sulfenic acid + pyruvate + NH3
-
5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(butyl)-L-cysteine sulfoxide
butane-1-sulfenic acid + pyruvate + NH3
-
6.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(propyl)-L-cysteine sulfoxide
propyl-1-sulfenic acid + pyruvate + NH3
-
4% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(propyl)-L-cysteine sulfoxide
propyl-1-sulfenic acid + pyruvate + NH3
-
about 20% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(propyl)-L-cysteine sulfoxide
propyl-1-sulfenic acid + pyruvate + NH3
-
about 5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(propyl)-L-cysteine sulfoxide
propyl-1-sulfenic acid + pyruvate + NH3
-
3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(propyl)-L-cysteine sulfoxide
propyl-1-sulfenic acid + pyruvate + NH3
-
about 5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(propyl)-L-cysteine sulfoxide
propyl-1-sulfenic acid + pyruvate + NH3
-
3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(propyl)-L-cysteine sulfoxide
propyl-1-sulfenic acid + pyruvate + NH3
-
about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(propyl)-L-cysteine sulfoxide
propyl-1-sulfenic acid + pyruvate + NH3
-
7% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-(propyl)-L-cysteine sulfoxide
propyl-1-sulfenic acid + pyruvate + NH3
-
3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(+/-)-alliin
allicin + pyruvic acid + NH3
-
carbon-sulfur (C-S) bond lyase activity of alliinase and catalytic alliinase-specific variable domain of the heavy chain of a heavy-chain antibodies, VHHs, overview
-
-
?
(+/-)-alliin
allicin + pyruvic acid + NH3
-
isolated from garlic and synthetic substrate (S)-allyl-L-cysteine sulfoxide
i.e. 2-propenyl 2-propenethiosulfinate
-
?
(+/-)-alliin
allicin + pyruvic acid + NH3
-
rapid, but thermolabil enzyme reaction
-
-
?
(+/-)-alliin
allicin + pyruvic acid + NH3
-
i.e. (+/-)-S-allyl-L-cysteine sulfoxide, the enzyme is more selectively for (-)-alliin than for (+)-alliin, a naturally occurring substrate for plant alliinase
-
-
?
(+/-)-alliin
allicin + pyruvic acid + NH3
-
i.e. (+/-)-S-allyl-L-cysteine sulfoxide, the enzyme is more selectively for (-)-alliin than for (+)-alliin, a naturally occurring substrate for plant alliinase
-
-
?
(-)-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(-)-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(-)-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(-)-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
about 20% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(-)-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(-)-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
about 3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(-)-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(-)-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(-)-(2-propenyl)-L-cysteine sulfoxide
2-propene-thioic acid + pyruvate + ammonia
-
about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
-
?
(-)-alliin
allicin + pyruvic acid + NH3
-
isolated from garlic and synthetic substrate (S)-allyl-L-cysteine sulfoxide
i.e. 2-propenyl 2-propenethiosulfinate
-
?
(-)-alliin
allicin + pyruvic acid + NH3
-
i.e. (-)-S-allyl-L-cysteine sulfoxide, the enzyme is more selectively for (-)-alliin than for (+)-alliin, the enzyme can selectively decompose (-)-alliin, whereas the level of (+)-alliin remains unchanged at least during 30-min incubation
-
-
?
(-)-alliin
allicin + pyruvic acid + NH3
-
i.e. (-)-S-allyl-L-cysteine sulfoxide, best substrate, the enzyme is more selectively for (-)-alliin than for (+)-alliin, a naturally occurring substrate for plant alliinase
-
-
?
(S)-(2-pyrrolyl)cysteine
2-pyrrolesulfenic acid + 2-aminoacrylate
-
-
precursor of the orange-red pigment formed upon wounding. Two molecules of 2-pyrrolesulfenic acid give rise to highly reactive S-(2-pyrrolyl)2-pyrrolethiosulfinate which in turn converts into red 2,2'-epidithio-3,3'-dipyrrole (dipyrrolo[2,3-d:2',3'-e]-1,2-dithiin)
-
?
(S)-(2-pyrrolyl)cysteine
2-pyrrolesulfenic acid + 2-aminoacrylate
-
-
precursor of the orange-red pigment formed upon wounding. Two molecules of 2-pyrrolesulfenic acid give rise to highly reactive S-(2-pyrrolyl)2-pyrrolethiosulfinate which in turn converts into red 2,2'-epidithio-3,3'-dipyrrole (dipyrrolo[2,3-d:2',3'-e]-1,2-dithiin)
-
?
(S)-(2-pyrrolyl)cysteine S-oxide
2-pyrrolesulfenic acid + 2-aminoacrylate
-
-
precursor of the orange-red pigment formed upon wounding. Two molecules of 2-pyrrolesulfenic acid give rise to highly reactive S-(2-pyrrolyl)2-pyrrolethiosulfinate which in turn converts into red 2,2'-epidithio-3,3'-dipyrrole (dipyrrolo[2,3-d:2',3'-e]-1,2-dithiin)
-
?
(S)-(2-pyrrolyl)cysteine S-oxide
2-pyrrolesulfenic acid + 2-aminoacrylate
-
-
precursor of the orange-red pigment formed upon wounding. Two molecules of 2-pyrrolesulfenic acid give rise to highly reactive S-(2-pyrrolyl)2-pyrrolethiosulfinate which in turn converts into red 2,2'-epidithio-3,3'-dipyrrole (dipyrrolo[2,3-d:2',3'-e]-1,2-dithiin)
-
?
(S)-(3-pyrrolyl)cysteine S-oxide
3-pyrrolesulfenic acid + 2-aminoacrylate
-
-
-
-
?
(S)-(3-pyrrolyl)cysteine S-oxide
3-pyrrolesulfenic acid + 2-aminoacrylate
-
-
-
-
?
2 alliin + H2O
allicin + 2 pyruvate + 2 NH3
-
higher affinity of immobilized enzyme toward its substrate
-
-
?
2 S-ethyl-L-Cys sulfoxide + H2O
ethyl ethanethiosulfinate + 2 pyruvate + 2 NH3
-
-
-
-
?
2 S-ethyl-L-Cys sulfoxide + H2O
ethyl ethanethiosulfinate + 2 pyruvate + 2 NH3
-
-
-
-
?
2 S-ethyl-L-Cys sulfoxide + H2O
ethyl ethanethiosulfinate + 2 pyruvate + 2 NH3
-
-
-
-
?
2 S-ethyl-L-Cys sulfoxide + H2O
ethyl ethanethiosulfinate + 2 pyruvate + 2 NH3
-
-
-
-
?
2 S-ethyl-L-Cys sulfoxide + H2O
ethyl ethanethiosulfinate + 2 pyruvate + 2 NH3
-
-
-
-
?
2 S-ethyl-L-Cys sulfoxide + H2O
ethyl ethanethiosulfinate + 2 pyruvate + 2 NH3
-
5% of the activity with desglutamyl-lentinic acid
-
-
?
2 S-ethyl-L-Cys sulfoxide + H2O
ethyl ethanethiosulfinate + 2 pyruvate + 2 NH3
-
-
-
?
alliin
2-propene-thioic acid + pyruvate + NH4+
-
i.e. (2R)-3-(allylsulfinyl)-2-aminopropanoic acid
The sulfenic acid condenses with loss of water to form thiosulfinates. The alpha-aminoacrylic acid formed initially subsequently breaks down into pyruvate and ammonia
-
?
alliin
allylsulfenic acid + pyruvate + NH3
-
-
pure allicin has significantly stronger in vitro inhibitory effect on the growth of six tested fungi (Candida albicans, Cryputococcus neoformans, Trichophyton rubum, Microsporum gypseum, Microsporum canis and Epidermophyton floccosum) than alliin and alliinase
-
?
butiin
butane-1-sulfenic acid + pyruvate + NH3
-
about 5% of the activity with L-(+)-isoalliin
-
-
?
butiin
butane-1-sulfenic acid + pyruvate + NH3
Allium cepa * Allium altyncolicum
-
about 10% of the activity with L-(+)-isoalliin
-
-
?
butiin
butane-1-sulfenic acid + pyruvate + NH3
Allium cepa * Allium chevsuricum
-
about 5% of the activity with L-(+)-isoalliin
-
-
?
butiin
butane-1-sulfenic acid + pyruvate + NH3
Allium cepa * Allium globosum
-
about 15% of the activity with L-(+)-alliin
-
-
?
butiin
butane-1-sulfenic acid + pyruvate + NH3
Allium cepa * Allium oliquum
-
about 15% of the activity with L-(+)-isoalliin
-
-
?
butiin
butane-1-sulfenic acid + pyruvate + NH3
Allium cepa * Allium saxatile
-
about 15% of the activity with L-(+)-alliin
-
-
?
butiin
butane-1-sulfenic acid + pyruvate + NH3
Allium cepa * Allium senescens
-
about 5% of the activity with L-(+)-isoalliin
-
-
?
ethiin
ethanesulfenic acid + pyruvate + NH3
-
about 5% of the activity with L-(+)-isoalliin
-
-
?
ethiin
ethanesulfenic acid + pyruvate + NH3
Allium cepa * Allium altyncolicum
-
about 5% of the activity with L-(+)-isoalliin
-
-
?
ethiin
ethanesulfenic acid + pyruvate + NH3
Allium cepa * Allium chevsuricum
-
about 5% of the activity with L-(+)-isoalliin
-
-
?
ethiin
ethanesulfenic acid + pyruvate + NH3
Allium cepa * Allium globosum
-
about 20% of the activity with L-(+)-alliin
-
-
?
ethiin
ethanesulfenic acid + pyruvate + NH3
Allium cepa * Allium oliquum
-
about 5% of the activity with L-(+)-isoalliin
-
-
?
ethiin
ethanesulfenic acid + pyruvate + NH3
Allium cepa * Allium saxatile
-
about 20% of the activity with L-(+)-alliin
-
-
?
ethiin
ethanesulfenic acid + pyruvate + NH3
Allium cepa * Allium senescens
-
about 5% of the activity with L-(+)-isoalliin
-
-
?
L-(+)-alliin
2-propene-thioic acid + pyruvate + NH4+
-
about 60% of the activity with L-(+)-isoalliin
-
-
?
L-(+)-alliin
2-propene-thioic acid + pyruvate + NH4+
Allium cepa * Allium altyncolicum
-
about 60% of the activity with L-(+)-isoalliin
-
-
?
L-(+)-alliin
2-propene-thioic acid + pyruvate + NH4+
Allium cepa * Allium chevsuricum
-
about 60% of the activity with L-(+)-isoalliin
-
-
?
L-(+)-alli