4.2.3.124: 2-deoxy-scyllo-inosose synthase
This is an abbreviated version!
For detailed information about 2-deoxy-scyllo-inosose synthase, go to the full flat file.
Word Map on EC 4.2.3.124
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4.2.3.124
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aminoglycoside
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circulans
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2-deoxystreptamine-containing
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2-deoxystreptamine
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carbocycle
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butirosin
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aminocyclitols
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dehydroquinate
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butirosin-producing
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aglycon
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kanamycin
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neomycin
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tobramycin
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actinomycete
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gentamicin
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nad+
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catechol
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tenebrarius
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cyclization
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micromonospora
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amacs
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aminoglycoside-aminocyclitols
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benzenoid
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shikimate
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industry
- 4.2.3.124
- aminoglycoside
- circulans
-
2-deoxystreptamine-containing
- 2-deoxystreptamine
-
carbocycle
- butirosin
-
aminocyclitols
- dehydroquinate
-
butirosin-producing
-
aglycon
- kanamycin
- neomycin
- tobramycin
-
actinomycete
- gentamicin
- nad+
- catechol
- tenebrarius
-
cyclization
- micromonospora
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amacs
- aminoglycoside-aminocyclitols
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benzenoid
- shikimate
- industry
Reaction
Synonyms
AlloH, btrC, BtrC2, DOI synthase, DOIS, KanA, kanC, neoC, tbmA
ECTree
Advanced search results
Reaction
Reaction on EC 4.2.3.124 - 2-deoxy-scyllo-inosose synthase
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D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
reaction mechanism, overview
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D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
reaction mechanism, overview
D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
reaction mechanism, overview
-
D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
reaction mechanism, overview
D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
catalyric reaction mechanism and substrate specificity, overview
D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
DOIS catalyzes the multi-step and direct cyclization reaction of G-6-P consisting five crucial transformations, which include the initial NAD+-dependent dehydrogenation at C-4, the elimination of a phosphate from C-5 and C-6, the hydride comeback to C-4 to form a cyclic enol ether, and the finial aldol-type intramolecular condensation between C-6 and C-1
D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
reaction and stereochemical mechanisms, overview
D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
reaction mechanism of the multistep reaction, stereochemistry of the phosphate elimination reaction, proceeding through syn-elimination assisted by Glu 243, and the cyclization, an aldol condensation that proceeds via a boat conformation, overview
D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
the reaction mechanism includes oxidation of C-4, beta-elimination of phosphate, reduction of C-4, ring opening, and intramolecular aldol cyclization. Completely conserved E243 of BtrC is catalytically involved in the phosphate elimination step
D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
reaction mechanism, overview
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D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
catalyric reaction mechanism and substrate specificity, overview
Niallia circulans SANK72073
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D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
reaction mechanism, overview
Niallia circulans SANK72073
-
-
D-glucose 6-phosphate = 2-deoxy-L-scyllo-inosose + phosphate
reaction mechanism of the multistep reaction, stereochemistry of the phosphate elimination reaction, proceeding through syn-elimination assisted by Glu 243, and the cyclization, an aldol condensation that proceeds via a boat conformation, overview
Niallia circulans SANK72073
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