4.2.3.3: methylglyoxal synthase
This is an abbreviated version!
For detailed information about methylglyoxal synthase, go to the full flat file.
Word Map on EC 4.2.3.3
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4.2.3.3
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meibomian
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glass
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film
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tear
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ocular
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eyelid
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gather
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grading
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grimace
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saccade
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dihydroxyacetone
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mongolian
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gerbil
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glory
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microgels
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monoglycerides
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dropout
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break-up
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1,2-propanediol
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ductility
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schirmer
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sire
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dhap
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polydactyly
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alloy
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phantom
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corrosion
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microtia
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orifice
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encephalocele
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cdt1
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orc6
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pre-replication
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synthesis
- 4.2.3.3
-
meibomian
-
glass
-
film
- tear
-
ocular
-
eyelid
-
gather
-
grading
-
grimace
-
saccade
- dihydroxyacetone
-
mongolian
- gerbil
-
glory
-
microgels
- monoglycerides
-
dropout
-
break-up
- 1,2-propanediol
-
ductility
-
schirmer
-
sire
- dhap
- polydactyly
-
alloy
-
phantom
-
corrosion
- microtia
-
orifice
- encephalocele
- cdt1
- orc6
-
pre-replication
- synthesis
Reaction
Synonyms
EC 4.2.99.11, methylglyoxal synthase, methylglyoxal synthetase, MGS, MgsA, msgA, synthase, methylglyoxal
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Reaction
Reaction on EC 4.2.3.3 - methylglyoxal synthase
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glycerone phosphate = 2-oxopropanal + phosphate
stereospecific deprotonation of the pro-S hydrogen at C-3 of dihydroxyacetone, the true product of the enzymatic reaction is the enol form of methylglyoxal which is ketonized in solution
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glycerone phosphate = 2-oxopropanal + phosphate
since the enzyme accepts the trans-enediol-phosphate as a substrate, it is likely that it or the trans-enediolate is an intermediate in the catalytic reaction with dihydroxyacetone phosphate
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