1.1.1.133: dTDP-4-dehydrorhamnose reductase

This is an abbreviated version, for detailed information about dTDP-4-dehydrorhamnose reductase, go to the full flat file.

Reaction

dTDP-beta-L-rhamnose
+
NADP+
=
dTDP-4-dehydro-beta-L-rhamnose
+
NADPH
+
H+

Synonyms

4-ketoreductase, bifunctional UDP-4-keto-6-deoxy-D-glucose epimerase/reductase, dTDP-4-dehydrorhamnose reductase, dTDP-4-keto-L-rhamnose reductase, dTDP-4-keto-rhamnose reductase, dTDP-4-ketorhamnose reductase, dTDP-6-deoxy-L-lyxo-4-hexulose reductase, dTDP-6-deoxy-L-mannose dehydrogenase, dTDP-L-rhamnose synthetase, RmlD, TDP-4-keto-rhamnose reductase, TDP-4-ketorhamnose reductase, thymidine diphosphate-4-dehydrorhamnose reductase, thymidine diphosphate-6-deoxy-L-talose, thymidine diphospho-4-ketorhamnose reductase, UGER

ECTree

     1 Oxidoreductases
         1.1 Acting on the CH-OH group of donors
             1.1.1 With NAD+ or NADP+ as acceptor
                1.1.1.133 dTDP-4-dehydrorhamnose reductase

Reaction

Reaction on EC 1.1.1.133 - dTDP-4-dehydrorhamnose reductase

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REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
dTDP-beta-L-rhamnose + NADP+ = dTDP-4-dehydro-beta-L-rhamnose + NADPH + H+
show the reaction diagram
in the reverse direction, reduction on the 4-position of the hexose moiety takes place only while the substrate is bound to another enzyme which catalyzes epimerization at C-3 and C-5; the complex has been referred to as dTDP-L-rhamnose synthase
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