1.1.1.133: dTDP-4-dehydrorhamnose reductase
This is an abbreviated version!
For detailed information about dTDP-4-dehydrorhamnose reductase, go to the full flat file.
Word Map on EC 1.1.1.133
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1.1.1.133
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dtdp-l-rhamnose
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actinobacillus
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dttp
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actinomycetemcomitans
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3,5-epimerase
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glucose-1-phosphate
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s-layer
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dtdp-4-keto-6-deoxy-d-glucose
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c-specific
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o-antigen
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deoxysugars
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alpha-d-glucose-1-phosphate
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dtdp-glucose-4,6-dehydratase
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dtdp-d-glucose
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thymidylyltransferase
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oleandomycin
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4,6-dehydratase
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synthesis
- 1.1.1.133
- dtdp-l-rhamnose
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actinobacillus
- dttp
- actinomycetemcomitans
-
3,5-epimerase
- glucose-1-phosphate
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s-layer
- dtdp-4-keto-6-deoxy-d-glucose
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c-specific
-
o-antigen
-
deoxysugars
- alpha-d-glucose-1-phosphate
- dtdp-glucose-4,6-dehydratase
- dtdp-d-glucose
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thymidylyltransferase
- oleandomycin
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4,6-dehydratase
- synthesis
Reaction
Synonyms
4-ketoreductase, Agl14, bifunctional UDP-4-keto-6-deoxy-D-glucose epimerase/reductase, dTDP-4-dehydrorhamnose reductase, dTDP-4-keto-L-rhamnose reductase, dTDP-4-keto-rhamnose reductase, dTDP-4-ketorhamnose reductase, dTDP-6-deoxy-L-lyxo-4-hexulose reductase, dTDP-6-deoxy-L-mannose dehydrogenase, dTDP-L-rhamnose synthetase, gacA, RfbD, RmlD, TDP-4-keto-rhamnose reductase, TDP-4-ketorhamnose reductase, thymidine diphosphate-4-dehydrorhamnose reductase, thymidine diphosphate-6-deoxy-L-talose, thymidine diphospho-4-ketorhamnose reductase, UGER
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Substrates Products
Substrates Products on EC 1.1.1.133 - dTDP-4-dehydrorhamnose reductase
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REACTION DIAGRAM
dTDP-4-dehydro-6-deoxy-D-glucose + NADPH
dTDP-beta-L-rhamnose + NADP+
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?
dTDP-4-dehydro-6-deoxy-D-glucose + NADPH + H+
dTDP-L-rhamnose + NADP+
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-
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?
dTDP-6-deoxy-L-lyxo-4-hexulose + NAD(P)H
dTDP-L-rhamnose + NAD(P)+
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-
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r
UDP-4-dehydro-6-deoxy-D-glucose + NADPH
UDP-beta-L-rhamnose + NADP+
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-
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?
UDP-4-keto-6-deoxy-D-glucose + NADPH + H+
UDP-L-rhamnose + NADP+
E3VXL5
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product identification by electrospray ionization-mass spectrometry and gas chromatography mass spectrometry
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?
additional information
?
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no substrate: GDP-4-keto-6-deoxy-mannose, UDP-glucose, dTDP-glucose, UDP-xylose, GDP-fucose
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-
?
dTDP-beta-L-rhamnose + NAD+
40% of the rate with NADPH
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?
dTDP-4-dehydro-6-deoxy-D-glucose + NADH + H+
dTDP-beta-L-rhamnose + NAD+
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?
dTDP-beta-L-rhamnose + NADP+
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-
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?
dTDP-4-dehydro-beta-L-rhamnose + NADPH + H+
dTDP-beta-L-rhamnose + NADP+
enzyme in the dTDP-beta-L-rhamnose-biosynthetic pathway
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?
dTDP-L-rhamnose + NADP+
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-
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?
dTDP-6-deoxy-L-lyxo-4-hexulose + NADPH
dTDP-L-rhamnose + NADP+
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-
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?
dTDP-6-deoxy-L-lyxo-4-hexulose + NADPH
dTDP-L-rhamnose + NADP+
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synthesis of L-rhamnose precurser dTDP-L-rhamnose, essential cell wall component of pathogenic bacteria
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?
dTDP-6-deoxy-L-lyxo-4-hexulose + NADPH
dTDP-L-rhamnose + NADP+
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synthesis of L-rhamnose precurser dTDP-L-rhamnose, essential cell wall component of pathogenic bacteria
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?
dTDP-6-deoxy-L-lyxo-4-hexulose + NADPH
dTDP-L-rhamnose + NADP+
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synthesis of L-rhamnose precurser dTDP-L-rhamnose, essential cell wall component of pathogenic bacteria
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?
dTDP-6-deoxy-L-lyxo-4-hexulose + NADPH
dTDP-L-rhamnose + NADP+
Streptomyces mutans
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synthesis of L-rhamnose precurser dTDP-L-rhamnose, essential cell wall component of pathogenic bacteria
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?
dTDP-6-deoxy-L-lyxo-4-hexulose + NADPH
dTDP-L-rhamnose + NADP+
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synthesis of L-rhamnose precurser dTDP-L-rhamnose, essential cell wall component of pathogenic bacteria
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?
dTDP-4-dehydro-6-deoxy-L-mannose + NADPH
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?
dTDP-6-deoxy-L-mannose + NADP+
dTDP-4-dehydro-6-deoxy-L-mannose + NADPH
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?
dTDP-6-deoxy-L-mannose + NADP+
dTDP-4-dehydro-6-deoxy-L-mannose + NADPH
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biosynthetic pathway, overview
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?
dTDP-4-dehydro-beta-L-rhamnose + NADPH + H+
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?
dTDP-beta-L-rhamnose + NADP+
dTDP-4-dehydro-beta-L-rhamnose + NADPH + H+
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?