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Information on EC 2.4.1.195 - N-hydroxythioamide S-beta-glucosyltransferase

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EC Tree
     2 Transferases
         2.4 Glycosyltransferases
             2.4.1 Hexosyltransferases
                2.4.1.195 N-hydroxythioamide S-beta-glucosyltransferase
IUBMB Comments
The enzyme specifically glucosylates the thiohydroximate functional group. It is involved in the biosynthesis of glucosinolates in cruciferous plants, and acts on aliphatic, aromatic, and indolic substrates.
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The enzyme appears in viruses and cellular organisms
Synonyms
desulfoglucosinolate-uridine diphosphate glucosyltransferase, thiohydroximate beta-D-glucosyltransferase, uridine diphosphoglucose (UDPglucose):thiohydroximate glucosyltransferase, uridine diphosphoglucose-thiohydroximate glucosyltransferase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
UDP-alpha-D-glucose + (E)-2-(1H-indol-3-yl)-1-thioacetohydroximate = UDP + desulfoglucobrassicin
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(3)
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0
UDP-alpha-D-glucose + (Z)-2-phenyl-1-thioacetohydroximate = UDP + desulfoglucotropeolin
show the reaction diagram
(1)
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0
UDP-alpha-D-glucose + an (E)-omega-(methylsulfanyl)alkyl-thiohydroximate = UDP + an aliphatic desulfoglucosinolate
show the reaction diagram
(2)
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0
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