4.5.1.B1: hexachlorocyclohexane dehydrochlorinase

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For detailed information about hexachlorocyclohexane dehydrochlorinase, go to the full flat file.

Word Map on EC 4.5.1.B1

4.5.1.B1

dehydrochlorination

paucimobilis

enantiomer

sphingobium

indicum

lindane

enantioselectivity

insecticide

pesticide

1,2,4-trichlorobenzene

hexabromocyclododecanes

hbcds

archetypal

stockholm

dehalogenase

Reaction

Synonyms

dehydrochlorinase, gamma-HCH dehydrochlorinase, gamma-hexachlorocyclohexane dehydrochlorinase, HCH dehydrochlorinase, LinA, LinA-type1, LinA-type2, LinA-UT26, Lina1, Lina2

ECTree

4 Lyases

4.5 Carbon-halide lyases

4.5.1 Carbon-halide lyases (only sub-subclass identified to date)

4.5.1.B1 hexachlorocyclohexane dehydrochlorinase

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Results	in table
15	AA Sequence
6	Cloned(Commentary)
2	Crystallization (Commentary)
7	General Information
9	Localization
3	Molecular Weight [Da]
2	Natural Substrates/ Products (Substrates)
43	Organism
2	pH Optimum
2	Purification (Commentary)
2	Reaction
28	Reference
66	Substrates and Products (Substrate)
12	Subunits
62	Synonyms
3	Temperature Optimum [°C]
2	Temperature Range [°C]
6	Temperature Stability [°C]

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General Information on EC 4.5.1.B1 - hexachlorocyclohexane dehydrochlorinase

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evolution

uncultured bacterium

B5ANU3, B5ANV6

changed residues K20Q, L96C and A131G, vicinal to the active site, are probably responsible for the altered enantioselectivity of LinA-type2 compared to LinA-type1, structural comparison of LinA-type2 and -type1 proteins suggests that thermostability of LinA-type2 might partly arise due to presence of higher number of ionic interactions, along with 4% increase in the intersubunit buried surface area

730715

metabolism

3 entries

additional information

5 entries