EC Number |
Reaction |
Reference |
---|
4.4.1.11 | L-methionine + H2O = methanethiol + NH3 + 2-oxobutanoate |
cleavage of C-N bond in addition to C-S, C-Se and C-O bond at beta-position of amino acids by elimination and replacement reactions |
34516, 34534 |
4.4.1.11 | L-methionine + H2O = methanethiol + NH3 + 2-oxobutanoate |
gamma-elimination reaction mechanism and intermediates, overview |
729320 |
4.4.1.11 | L-methionine + H2O = methanethiol + NH3 + 2-oxobutanoate |
mechanism |
34523, 34530 |
4.4.1.11 | L-methionine + H2O = methanethiol + NH3 + 2-oxobutanoate |
rate determining stage of the enzymatic reaction is deamination of aminocrotonate, important contribution of the sulfur atom and methylene groups to the efficiency of binding of substrates and inhibitors |
714123 |