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The enzyme participates in a widespread glutathione-mediated detoxification pathway. In animals the activity is usually catalysed by enzymes that have numerous additional activities, such as EC 126.96.36.199, leucyl aminopeptidase, EC 188.8.131.52, membrane alanyl aminopeptidase, and EC 184.108.40.206, membrane dipeptidase. However, in the bacterium Corynebacterium sp. Ax20, which degrades axillary secretions, the enzyme appears to be specific for this task.