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Information on EC 1.13.11.50 - acetylacetone-cleaving enzyme

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EC Tree
IUBMB Comments
An Fe(II)-dependent enzyme. Forms the first step in the acetylacetone degradation pathway of Acinetobacter johnsonii. While acetylacetone is by far the best substrate, heptane-3,5-dione, octane-2,4-dione, 2-acetylcyclohexanone and ethyl acetoacetate can also act as substrates.
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Word Map
The enzyme appears in viruses and cellular organisms
Synonyms
diketone cleaving enzyme, acetylacetone dioxygenase, acetylacetone-cleaving enzyme, diketone dioxygenase, diketone-cleaving dioxygenase, diketone cleaving dioxygenase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
pentane-2,4-dione + O2 = acetate + 2-oxopropanal
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