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1.14.15.26: toluene methyl-monooxygenase

This is an abbreviated version!
For detailed information about toluene methyl-monooxygenase, go to the full flat file.

Reaction

m-xylene
+
O2
+ 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+ =
3-methylbenzyl alcohol
+ 2 oxidized ferredoxin [iron-sulfur] cluster +
H2O

Synonyms

ntnM, xylM

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.15 With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.15.26 toluene methyl-monooxygenase

Substrates Products

Substrates Products on EC 1.14.15.26 - toluene methyl-monooxygenase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
2-fluorotoluene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
2-fluorobenzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
3-chlorotoluene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
3-chlorobenzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
3-fluorotoluene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
3-fluorobenzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
3-methyltoluene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
3-methylbenzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
4-chlorotoluene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
4-chlorobenzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
4-fluorotoluene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
4-fluorobenzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
-
-
-
-
?
4-methyltoluene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
4-methylbenzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
-
-
-
-
?
m-xylene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
3-methylbenzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
-
-
-
?
o-xylene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
2-methylbenzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
-
-
-
?
p-xylene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
4-methylbenzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
-
-
-
?
toluene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+
benzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram