EC Number   |
Substrates |
Organism |
Products |
Reversibility |
|---|
   4.2.3.107 | (3R)-linalyl diphosphate |
- |
Pinus contorta |
? + diphosphate |
the velocity of the reaction with the (3S)-linalyl enantiomer is 25fold greater than the velocity with the (3R)-enantiomer and twice that of the natural substrate, geranyl diphosphate. Cyclization of the linalyl intermediate is faster than the coupled isomerization and cyclization of the geranyl substrate |
? |
| 4.2.3.107 | (3R)-linalyl diphosphate |
- |
Pinus contorta |
myrcene + diphosphate |
- |
? |
| 4.2.3.107 | (3S)-linalyl diphosphate |
- |
Pinus contorta |
(+)-car-3-ene + diphosphate |
more than 99.9% optically pure |
? |
| 4.2.3.107 | (3S)-linalyl diphosphate |
- |
Pinus contorta |
? + diphosphate |
the velocity of the reaction with the (3S)-linalyl enantiomer is 25fold greater than the velocity with the (3R)-enantiomer and twice that of the natural substrate, geranyl diphosphate. Cyclization of the linalyl intermediate is faster than the coupled isomerization and cyclization of the geranyl substrate |
? |
| 4.2.3.107 | geranyl diphosphate |
- |
Lavandula x intermedia |
(+)-car-3-ene + diphosphate |
- |
? |
| 4.2.3.107 | geranyl diphosphate |
- |
Salvia stenophylla |
(+)-car-3-ene + diphosphate |
73% (+)-3-carene, 13% (-)-limonene, 6% myrcene, 4% 4-carene and 1% beta-phellandrene |
? |
| 4.2.3.107 | geranyl diphosphate |
- |
Picea abies |
(+)-car-3-ene + diphosphate |
78% (+)-car-3-ene plus 11% terpinolene plus minor products. No detection of (-)-car-3-ene |
? |
| 4.2.3.107 | geranyl diphosphate |
- |
Picea sitchensis |
(+)-car-3-ene + diphosphate |
major product, plus some terpinolene |
? |
| 4.2.3.107 | geranyl diphosphate |
- |
Picea sitchensis |
(+)-car-3-ene + diphosphate |
wild-type produces 46.2% (+)-car-3-ene, 8.8% (-)-sabinene, 29.7% terpinolene |
? |
| 4.2.3.107 | geranyl diphosphate |
- |
Picea sitchensis |
(+)-car-3-ene + diphosphate |
wild-type produces 49% (+)-car-3-ene, 8.7% (-)-sabinene, 24.7% terpinolene |
? |
