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EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13R)-13-hydroperoxy-9,11-octadecadienoate is utilized more slowly than (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate - Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate an essentially complete loss of isotope is noted with the (14R)-deuterated precursor, whereas incubation of the (14S)-deuterated precursor affords products that retain most of the deuterium label Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate an essentially complete loss of isotope is noted with the (14R)-deuterated precursor, whereas incubation of the (14S)-deuterated precursor affords products that retained most of the deuterium label Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate no activity with (9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate the enzyme uses preferentially 13-hydroperoxides as substrates and efficiently converts them into divinyl ether fatty acids Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate the S enantiomer is a much better substrate for the divinyl ether synthase compared to the R enantiomer. Incubation of (9Z,11E,13S)-[18O2]hydroperoxy-9,11-octadecadienoic acid leads to the formation of etheroleic acid which retains 18O in the ether oxygen. An intermediary role of an epoxyallylic cation in etheroleic acid biosynthesis is postulated Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + (9E,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O two isomers of etheroleic acid are isolated ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate - Allium sativum (9Z,11E)-12-[(1E,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etherolenic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8more irrespective of which hydroperoxide regioisomer serves as the substrate, divinyl ether synthases abstracting the pro-R hydrogen generate divinyl ethers having an E vinyl ether double bond, whereas enzymes abstracting the pro-S hydrogen produce divinyl ethers having a Z vinyl ether double bond Allium sativum ? - ?
Display the reaction diagram Show all sequences 4.2.1.B8more low activity with 13-hydroperoxy-octadecatrienoate Allium sativum ? - ?
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