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EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate - Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid - Ranunculus acris (9Z,11E)-12-[(1'Z)-hexenyloxy]-9,11-dodecadienoic acid i.e. (omega5Z)-etherolenic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate - Allium sativum (9Z,11E)-12-[(1E,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etherolenic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate is the preferred substrate Convallaria majalis (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate an essentially complete loss of isotope is noted with the (14R)-deuterated precursor, whereas incubation of the (14S)-deuterated precursor affords products that retain most of the deuterium label Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate an essentially complete loss of isotope is noted with the (14R)-deuterated precursor, whereas incubation of the (14S)-deuterated precursor affords products that retained most of the deuterium label Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate highly preferred substrate Ranunculus acris (9Z,11E)-12-[(1'Z,3'Z)-hexadienyloxy]-9,11-dodecadienoate + H2O i.e. etherolenic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid i.e. 13-HPOD Selaginella moellendorffii (9Z,11E)-12[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O - ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoic acid i.e. 13-HPOT Selaginella moellendorffii (9Z,11E)-12[(1Z,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O - ?
Display the reaction diagram Show all sequences 4.2.1.B8more irrespective of which hydroperoxide regioisomer serves as the substrate, divinyl ether synthases abstracting the pro-R hydrogen generate divinyl ethers having an E vinyl ether double bond, whereas enzymes abstracting the pro-S hydrogen produce divinyl ethers having a Z vinyl ether double bond Allium sativum ? - ?
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