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EC Number	Substrates	Commentary Substrates	Organism	Products	Commentary (Products)	Reversibility
4.1.99.24	L-tyrosine + D-ribulose 5-phosphate	-	Xenorhabdus nematophila	(2S)-3-(4-hydroxyphenyl)-2-isocyanopropanoate + hydroxyacetone + formaldehyde + phosphate + H2O	-	?
4.1.99.24	L-tyrosine + D-ribulose 5-phosphate	according to the proposed mechanism, the enzyme forms an imine intermediate composed of linked L-tyrosine and D-ribulose 5-phosphate, followed by loss of the phosphate group and formation of a beta-keto imine and keto-enol tautomerization. This is followed by a C-C bond cleavage, the release of hydroxyacetone, and a retro aldol type reaction that releases formaldehyde and forms the final product	Xenorhabdus nematophila	(2S)-3-(4-hydroxyphenyl)-2-isocyanopropanoate + hydroxyacetone + formaldehyde + phosphate + H2O	-	?

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Release 2023.1 (January 2023)