EC Number   |
Substrates |
Organism  |
Products |
Reversibility |
|---|
   4.2.3.82 | (2E,6E)-farnesyl diphosphate |
- |
Clausena lansium |
(+)-alpha-santalene + diphosphate |
- |
? |
| 4.2.3.82 | 2 (2E,6E)-farnesyl diphosphate |
- |
Clausena lansium |
(+)-alpha-santalene + trans-alpha-bergamotene + 2 diphosphate |
amounts of the sesquiterpenes alpha-santalene and trans-alpha-bergamotene produced are,respectively,1.45 and0.177 mg/l |
? |
| 4.2.3.82 | more |
the enzyme produces high amonuts of (+)-alpha-santalene from (2E,6E)-farnesyl diphosphate, and traces of (-)-exo-alpha-bergamotene |
Clausena lansium |
? |
- |
? |
| 4.2.3.82 | more |
the enzyme produces high amonuts of alpha-santalene from (2E,6E)-farnesyl diphosphate, and traces of (-)-exo-alpha-bergamotene. The enzyme assay is coupled to the inorganic diphosphatase (IPP1) from Saccharomyces cerevisiae. Compound identification and quantification by GC-MS and NMR analysis |
Clausena lansium |
? |
- |
? |
| 4.2.3.82 | (2E,6E)-farnesyl diphosphate |
- |
Santalum album |
(+)-alpha-santalene + diphosphate |
- |
? |
| 4.2.3.82 | (2E,6E)-farnesyl diphosphate |
when incubated in the presence of 10 mM Mg2+ the enzyme converts (2E,6E)-farnesyl diphosphate into alpha-santalene, beta-santalene and epi-beta-santalene,alpha-exo-bergamotene, as well as traces of alpha-farnesene and beta-farnesene. Incubations with Mn2+ yields mainly alpha-exo-bergamotene |
Santalum album |
(+)-alpha-santalene + diphosphate |
- |
? |
| 4.2.3.82 | (2E,6E)-farnesyl diphosphate |
when incubated in the presence of 10 mM Mg2+ the enzyme converts (2Z,6Z)-farnesyl diphosphate into alpha-endo-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene and beta-santalene |
Santalum album |
(+)-alpha-santalene + diphosphate |
- |
? |
| 4.2.3.82 | (2E,6E)-farnesyl diphosphate |
- |
Santalum album |
alpha-santalene + diphosphate |
products are alpha-santalene, beta-, and epi-beta-santalene, exo-alpha-bergamotene, as well as traces of alpha- and beta-farnesene |
? |
| 4.2.3.82 | (2E,6E)-farnesyl diphosphate |
- |
Santalum album |
alpha-santalene + diphosphate |
synthesis of a mixture of sesquiterpenes namely alpha-santalene, beta-santalene, epi-beta-santalene and alpha-bergamotene |
? |
| 4.2.3.82 | more |
Santalum album Ssy also accepts (2Z,6Z)-farnesyl diphosphate as substrate, producing a mixture of alpha-endo-bergamotene, alpha-santalene, (Z)-beta-farnesene, epi-beta-santalene, and beta-santalene. With substrate geranyl diphosphate, products are linalool, geraniol, and terpineol along with traces of alpha-pinene and camphene. The product profile resulting from incubations of SaSSy with (E,E)-FPP resembles the authentic essential oil of Santalum album more closely than that of the (Z,Z)-FPP incubations |
Santalum album |
? |
- |
? |
