Organism | UniProt | Comment | Textmining |
---|---|---|---|
Solidago canadensis | - |
- |
- |
Purification (Comment) | Organism |
---|---|
- |
Solidago canadensis |
Reaction | Comment | Organism | Reaction ID |
---|---|---|---|
(2E,6E)-farnesyl diphosphate = (+)-germacrene D + diphosphate | the initial step is abstraction of the diphosphate moiety under ring closure to yield germacrenyl cation. The next step is a 1,2-hydride shift of H-7 into the isopropyl group, generating a germacrenyl cation with the positive charge at position 7. The cation undergoes a 1,2-hydride shift of H-6 yielding a cation with positive charge at position 6. During this step the configuration at C-7 is fixed. Finally, the cation is deprotonated at C-15 and the positive charge is quenched by two electron pair shifts to generate (+)-germacrene D | Solidago canadensis |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
(2E,6E)-farnesyl diphosphate | - |
Solidago canadensis | (+)-germacrene D + diphosphate | - |
? |