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Literature summary for 4.2.3.20 extracted from

  • Bouwmeester, H.J.; Gershenzon, J.; Konings, M.C.J.M.; Croteau, R.
    Biosynthesis of the monoterpenes limonene and carvone in the fruit of caraway. I. Demonstration of enzyme activities and their changes with development (1998), Plant Physiol., 117, 901-912.
    View publication on PubMedView publication on EuropePMC

Localization

Localization Comment Organism GeneOntology No. Textmining
soluble
-
Carum carvi
-
-

Metals/Ions

Metals/Ions Comment Organism Structure
additional information divalent metal ion required, probably Mn2+ Carum carvi

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
geranyl diphosphate Carum carvi
-
(+)-(R)-limonene + diphosphate
-
?

Organism

Organism UniProt Comment Textmining
Carum carvi
-
-
-

Reaction

Reaction Comment Organism Reaction ID
geranyl diphosphate = (R)-limonene + diphosphate forms the first step of carvone biosynthesis in caraway Carum carvi

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
geranyl diphosphate
-
Carum carvi (+)-(R)-limonene + diphosphate
-
?
geranyl diphosphate
-
Carum carvi (+)-(R)-limonene + diphosphate high stereoselectivity, 98.4% of (+)-product ?

pH Optimum

pH Optimum Minimum pH Optimum Maximum Comment Organism
7.5
-
-
Carum carvi