Organism | UniProt | Comment | Textmining |
---|---|---|---|
Salmonella enterica subsp. enterica serovar Typhimurium | - |
- |
- |
Reaction | Comment | Organism | Reaction ID |
---|---|---|---|
2,3-dihydroxy-3-methylbutanoate = 3-methyl-2-oxobutanoate + H2O | stereochemistry, elimination and protonation steps are stereospecific, enol-keto conversion takes place with proton addition at C-3 to the same face of the enol as that of the departing hydroxy-group | Salmonella enterica subsp. enterica serovar Typhimurium |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
2,3-dihydroxy-3-methylbutanoate | no activity with 2S-2,3-dihydroxy-3-methylbutanoate | Salmonella enterica subsp. enterica serovar Typhimurium | 2-oxoisovalerate + H2O | - |
? | |
2,3-dihydroxy-3-methylbutanoate | 2R-2,3-dihydroxy-3-methylbutanoate | Salmonella enterica subsp. enterica serovar Typhimurium | 2-oxoisovalerate + H2O | - |
? | |
2,3-dihydroxy-3-methylpentanoate | 2R,3R-dihydroxy-3-methylpentanoate, 2R,3S-dihydroxy-3-methylpentanoate, no activity with isomers with 2S configuration | Salmonella enterica subsp. enterica serovar Typhimurium | 3-methyl-2-oxopentanoate + H2O | - |
? |