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EC Tree
IUBMB Comments Isolated from the bacterium Streptomyces pristinaespiralis.
The expected taxonomic range for this enzyme is: Bacteria, Eukaryota
Synonyms
pentalenene synthase,
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pentalenene synthase
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(2E,6E)-farnesyl diphosphate + H2O = (+)-(2S,3R,9R)-pristinol + diphosphate
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(2E,6E)-farnesyl-diphosphate diphosphate-lyase [cyclizing, (+)-(2S,3R,9R)-pristinol-forming]
Isolated from the bacterium Streptomyces pristinaespiralis.
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(2E,6E)-farnesyl diphosphate + H2O
(+)-(2S,3R,9R)-pristinol + diphosphate
additional information
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(2E,6E)-farnesyl diphosphate + H2O
(+)-(2S,3R,9R)-pristinol + diphosphate
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(2E,6E)-farnesyl diphosphate + H2O
(+)-(2S,3R,9R)-pristinol + diphosphate
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additional information
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possible reaction mechanisms start with the cyclization of farnesyl diphosphate to the humulyl cation, a 1,2-hydride shift, and capture with water to (R)-hyemalol. No substrates: geranyl diphosphate and geranylgeranyl diphosphate
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additional information
?
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possible reaction mechanisms start with the cyclization of farnesyl diphosphate to the humulyl cation, a 1,2-hydride shift, and capture with water to (R)-hyemalol. No substrates: geranyl diphosphate and geranylgeranyl diphosphate
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?
Please wait a moment until the data is sorted. This message will disappear when the data is sorted.
(2E,6E)-farnesyl diphosphate + H2O
(+)-(2S,3R,9R)-pristinol + diphosphate
additional information
?
-
(2E,6E)-farnesyl diphosphate + H2O
(+)-(2S,3R,9R)-pristinol + diphosphate
-
-
-
?
(2E,6E)-farnesyl diphosphate + H2O
(+)-(2S,3R,9R)-pristinol + diphosphate
-
-
-
?
additional information
?
-
possible reaction mechanisms start with the cyclization of farnesyl diphosphate to the humulyl cation, a 1,2-hydride shift, and capture with water to (R)-hyemalol. No substrates: geranyl diphosphate and geranylgeranyl diphosphate
-
-
?
additional information
?
-
possible reaction mechanisms start with the cyclization of farnesyl diphosphate to the humulyl cation, a 1,2-hydride shift, and capture with water to (R)-hyemalol. No substrates: geranyl diphosphate and geranylgeranyl diphosphate
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UniProt
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UniProt
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PRISS_STRE2
Streptomyces pristinaespiralis (strain ATCC 25486 / DSM 40338 / CBS 914.69 / JCM 4507 / NBRC 13074 / NRRL 2958 / 5647)
372
0
41393
Swiss-Prot
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TATC6_HYPAT
386
0
44939
Swiss-Prot
Mitochondrion (Reliability: 3 )
A0A5E7QX21_PSEFL
323
0
36792
TrEMBL
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A0A5E6XE42_PSEFL
323
0
36686
TrEMBL
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A0A5E7U6V5_PSEFL
323
0
36639
TrEMBL
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expression in Escherichia coli
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Klapschinski, T.A.; Rabe, P.; Dickschat, J.S.
Pristinol, a sesquiterpene alcohol with an unusual skeleton from Streptomyces pristinaespiralis
Angew. Chem. Int. Ed. Engl.
55
10141-10144
2016
Streptomyces pristinaespiralis (B5H7H3), Streptomyces pristinaespiralis ATCC 25 486 (B5H7H3)
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