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2.1.5.1: sesamin methylene transferase

This is an abbreviated version!
For detailed information about sesamin methylene transferase, go to the full flat file.

Reaction

(+)-demethylpiperitol
+
tetrahydrofolate
=
(+)-didemethylpinoresinol
+
5,10-methylenetetrahydrofolate

Synonyms

SesA

ECTree

     2 Transferases
         2.1 Transferring one-carbon groups
             2.1.5 Methylenetransferases
                2.1.5.1 sesamin methylene transferase

Substrates Products

Substrates Products on EC 2.1.5.1 - sesamin methylene transferase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(+)-demethylpiperitol + tetrahydrofolate
(+)-didemethylpinoresinol + 5,10-methylenetetrahydrofolate
show the reaction diagram
-
-
-
?
(+)-episesamin + tetrahydrofolate
4-[(1S,3aR,4R,6aR)-4-(2H-1,3-benzodioxol-5-yl)tetrahydro-1H,3H-furo[3,4-c]furan-1-yl]benzene-1,2-diol + 5,10-methylenetetrahydrofolate
show the reaction diagram
31% activity compared to (+)-sesamin
-
-
?
(+)-sesamin + tetrahydrofolate
(+)-demethylpiperitol + 5,10-methylenetetrahydrofolate
show the reaction diagram
100% activity
-
-
?
(+)-sesamolin + tetrahydrofolate
4-[(1S,3aR,4R,6aR)-4-[(2H-1,3-benzodioxol-5-yl)oxy]tetrahydro-1H,3H-furo[3,4-c]furan-1-yl]benzene-1,2-diol + 4-[[(1R,3aR,4S,6aR)-4-(2H-1,3-benzodioxol-5-yl)tetrahydro-1H,3H-furo[3,4-c]furan-1-yl]oxy]benzene-1,2-diol + 4-[(1S,3aR,4R,6aR)-4-(3,4-dihydroxyphenoxy)tetrahydro-1H,3H-furo[3,4-c]furan-1-yl]benzene-1,2-diol + 5,10-methylenetetrahydrofolate
show the reaction diagram
97% activity compared to (+)-sesamin
-
-
?
(-)-asarinin + tetrahydrofolate
4-[(1S,3aS,4R,6aS)-4-(2H-1,3-benzodioxol-5-yl)tetrahydro-1H,3H-furo[3,4-c]furan-1-yl]benzene-1,2-diol + 4,4'-[(1R,3aS,4S,6aS)-tetrahydro-1H,3H-furo[3,4-c]furan-1,4-diyl]di(benzene-1,2-diol) + 5,10-methylenetetrahydrofolate
show the reaction diagram
88% activity compared to (+)-sesamin
-
-
?
piperine + tetrahydrofolate
(2E,4E)-5-(3,4-dihydroxyphenyl)-1-(piperidin-1-yl)penta-2,4-dien-1-one + 5,10-methylenetetrahydrofolate
show the reaction diagram
11% activity compared to (+)-sesamin
-
-
?
sesaminol + tetrahydrofolate
4-[(1S,3aR,4S,6aR)-4-(6-hydroxy-2H-1,3-benzodioxol-5-yl)tetrahydro-1H,3H-furo[3,4-c]furan-1-yl]benzene-1,2-diol + 5-[(1S,3aR,4S,6aR)-4-(3,4-dihydroxyphenyl)tetrahydro-1H,3H-furo[3,4-c]furan-1-yl]benzene-1,2,4-triol + 5,10-methylenetetrahydrofolate
show the reaction diagram
112% activity compared to (+)-sesamin
-
-
?