1.17.98.2: bacteriochlorophyllide c C-71-hydroxylase

This is an abbreviated version!
For detailed information about bacteriochlorophyllide c C-71-hydroxylase, go to the full flat file.

Reaction

2 S-adenosyl-L-methionine +

Synonyms

7-methyl bacteriochlorophyllide c oxygenase, bciD

ECTree

     1 Oxidoreductases

         1.17 Acting on CH or CH₂ groups

             1.17.98 With other, known, physiological acceptors

                1.17.98.2 bacteriochlorophyllide c C-71-hydroxylase

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Systematic Name

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Systematic Name on EC 1.17.98.2 - bacteriochlorophyllide c C-71-hydroxylase

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SYSTEMATIC NAME

IUBMB Comments

bacteriochlorophyllide-c:S-adenosyl-L-methionine oxidoreductase (C-71-hydroxylating)

The enzyme, found in green sulfur bacteria (Chlorobiaceae), is a radical S-adenosyl-L-methionine (AdoMet) enzyme and contains a [4Fe-4S] cluster. It catalyses two consecutive hydroxylation reactions of the C-7 methyl group of bacteriochlorophyllide c to form a geminal diol intermediate that spontaneously dehydrates to produce the formyl group of bacteriochlorophyllide e.