1.14.14.42: homomethionine N-monooxygenase
This is an abbreviated version!
For detailed information about homomethionine N-monooxygenase, go to the full flat file.
Word Map on EC 1.14.14.42
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1.14.14.42
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glucosinolates
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cyp83a1
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brassica
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glucoraphanin
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cabbage
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auxin
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ugt74b1
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oleraceae
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broccoli
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methionine-derived
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gluconapin
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sulforaphane
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brassicales
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brassicaceae
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silique
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chain-elongated
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oximes
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aldoximes
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sinigrin
- 1.14.14.42
- glucosinolates
- cyp83a1
- brassica
- glucoraphanin
- cabbage
- auxin
-
ugt74b1
-
oleraceae
- broccoli
-
methionine-derived
- gluconapin
- sulforaphane
- brassicales
- brassicaceae
- silique
-
chain-elongated
- oximes
- aldoximes
- sinigrin
Reaction
Synonyms
CYP79F1, CYP79F2, dihomomethionine N-hydroxylase, hexahomomethionine N-hydroxylase
ECTree
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Systematic Name
Systematic Name on EC 1.14.14.42 - homomethionine N-monooxygenase
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L-homomethionine,[NADPH-hemoprotein reductase]:oxygen oxidoreductase
This plant cytochrome P-450 (heme thiolate) enzyme is involved in methionine-derived aliphatic glucosinolates biosynthesis. It catalyses two successive N-hydroxylations, which are followed by dehydration and decarboxylation. CYP79F1 from Arabidopsis thaliana can metabolize mono-, di-, tri-, tetra-, penta-, and hexahomomethionine to their corresponding aldoximes, while CYP79F2 from the same plant can only metabolize penta- and hexahomomethionine.