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5.5.1.17: (S)-beta-macrocarpene synthase

This is an abbreviated version!
For detailed information about (S)-beta-macrocarpene synthase, go to the full flat file.

Reaction

(S)-beta-bisabolene
=
(S)-beta-macrocarpene

Synonyms

terpene synthase 11, terpene synthase 6, TPS11, TPS6

ECTree

     5 Isomerases
         5.5 Intramolecular lyases
             5.5.1 Intramolecular lyases (only sub-subclass identified to date)
                5.5.1.17 (S)-beta-macrocarpene synthase

Systematic Name

Systematic Name on EC 5.5.1.17 - (S)-beta-macrocarpene synthase

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SYSTEMATIC NAME
IUBMB Comments
(S)-beta-macrocarpene lyase (decyclizing)
The synthesis of (S)-beta-macrocarpene from (2E,6E)-farnesyl diphosphate proceeds in two steps. The first step is the cyclization to (S)-beta-bisabolene (cf. EC 4.2.3.55, (S)-beta-bisabolene synthase). The second step is the isomerization to (S)-beta-macrocarpene.