5.4.4.1: (hydroxyamino)benzene mutase
This is an abbreviated version!
For detailed information about (hydroxyamino)benzene mutase, go to the full flat file.
Word Map on EC 5.4.4.1
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5.4.4.1
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nitrobenzene
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2-aminophenol
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pseudoalcaligenes
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nitroreductase
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biocatalyst
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ring-fission
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nitroaromatic
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biocatalytic
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putida
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aminophenols
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synthesis
- 5.4.4.1
- nitrobenzene
- 2-aminophenol
- pseudoalcaligenes
- nitroreductase
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biocatalyst
-
ring-fission
-
nitroaromatic
-
biocatalytic
- putida
- aminophenols
- synthesis
Reaction
Synonyms
CnbB, HAB mutase, hydroxylaminobenzene hydroxymutase, hydroxylaminobenzene mutase
ECTree
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Reaction
Reaction on EC 5.4.4.1 - (hydroxyamino)benzene mutase
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intramolecular hydroxyl transfer
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(hydroxyamino)benzene = 2-aminophenol
proposed intramolecular rearrangment mechanism, different from the nonenzymatic Bamberger reaction which proceeds via intermolecular hydroxyl transfer
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