4.2.3.91: cubebol synthase
This is an abbreviated version!
For detailed information about cubebol synthase, go to the full flat file.
Reaction
Synonyms
Cop4
ECTree
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Metals Ions
Metals Ions on EC 4.2.3.91 - cubebol synthase
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K+
-
replacement of Mg2+ by Mn2+ results in loss of product beta-copaene. Presence of K+ decreases the (-)-germacrene D yield and instead increases the overall yield of tricyclic sesquiterpene olefins
Mn2+
-
replacement of Mg2+ by Mn2+ results in loss of product beta-copaene. In the presence of the Mn2+, Cop4 favors a reaction path that ends after one cyclization in (?)-germacrene D