4.2.3.37: epi-isozizaene synthase
This is an abbreviated version!
For detailed information about epi-isozizaene synthase, go to the full flat file.
Word Map on EC 4.2.3.37
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4.2.3.37
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cyclization
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sesquiterpene
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carbocation
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terpenoid
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coelicolor
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tricyclic
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contour
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multistep
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cyclases
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isoprenoid
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pyrophosphate
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remold
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cane
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terpene
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chemodiversity
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product-like
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bisphosphonate
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high-fidelity
- 4.2.3.37
-
cyclization
-
sesquiterpene
-
carbocation
-
terpenoid
- coelicolor
-
tricyclic
-
contour
-
multistep
-
cyclases
-
isoprenoid
- pyrophosphate
-
remold
-
cane
-
terpene
-
chemodiversity
-
product-like
- bisphosphonate
-
high-fidelity
Reaction
Synonyms
EIZS, epi-isozizaene synthase, SAV_3032, SCO5222 protein, TPS2
ECTree
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Reaction
Reaction on EC 4.2.3.37 - epi-isozizaene synthase
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(2E,6E)-farnesyl diphosphate = (+)-epi-isozizaene + diphosphate
ionization and isomerization of farnesyl diphosphate will give (3R)-nerolidyl diphosphate. Rotation about the newly generated C-2/C-3 bond generates the corresponding cisoid nerolidyl diphosphate conformer which can undergo ionization and cyclization to form a bisabolyl cation. Following 1,2-hydride shift and spirocyclization, the resultant acorenyl cation can undergo further cyclization, ring contraction, methyl migration, and deprotonation to yield (+)-epi-isozizaene
(2E,6E)-farnesyl diphosphate = (+)-epi-isozizaene + diphosphate
ionization and isomerization of farnesyl diphosphate will give (3R)-nerolidyl diphosphate. Rotation about the newly generated C-2/C-3 bond generates the corresponding cisoid nerolidyl diphosphate conformer which can undergo ionization and cyclization to form a bisabolyl cation. Following 1,2-hydride shift and spirocyclization, the resultant acorenyl cation can undergo further cyclization, ring contraction, methyl migration, and deprotonation to yield (+)-epi-isozizaene
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