4.2.3.144: geranyllinalool synthase
This is an abbreviated version!
For detailed information about geranyllinalool synthase, go to the full flat file.
Word Map on EC 4.2.3.144
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4.2.3.144
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synthases
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diterpene
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herbivore
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sesquiterpene
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terpenoids
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jasmonate
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angiosperm
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pollinators
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alamethicin
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ent-kaurene
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insect-induced
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plant-plant
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orchid
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limonene
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attenuata
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agriculture
- 4.2.3.144
- synthases
-
diterpene
-
herbivore
-
sesquiterpene
-
terpenoids
- jasmonate
-
angiosperm
-
pollinators
- alamethicin
- ent-kaurene
-
insect-induced
-
plant-plant
-
orchid
- limonene
- attenuata
- agriculture
Reaction
Synonyms
101262489, At1g61120, geranyllinalool synthase, GES, GLS, LnTPS3, More, NaGLS, SlGLS, SlTPS46, terpene synthase TPS4, TPS-e/f, TPS04/GES, TPS2, TPS46
ECTree
4.2.3.144 geranyllinalool synthaseAdvanced search results
results (
results (Substrates Products
Substrates Products on EC 4.2.3.144 - geranyllinalool synthase
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SUBSTRATE 
PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
(2E,6E)-farnesyl diphosphate + H2O
(3S,6E)-nerolidol + diphosphate
reaction of EC 4.2.3.48
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-
?
(2E,6E)-farnesyl diphosphate + H2O
trans-nerolidol + diphosphate
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-
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?
geranylgeranyl diphosphate + H2O
(6E,10E)-geranyllinalool + diphosphate
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-
-
?
geranylgeranyl diphosphate + H2O
(6E,10E)-geranyllinalool + diphosphate
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-
-
?
geranylgeranyl diphosphate + H2O
(6E,10E)-geranyllinalool + diphosphate
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-
-
?
geranylgeranyl diphosphate + H2O
(6E,10E)-geranyllinalool + diphosphate
preferred substrate
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-
?
geranylgeranyl diphosphate + H2O
(E,E)-geranyllinalool + diphosphate
the product (E,E)-geranyllinalool is a precursor to the volatile compound 4,8,12-trimethyl-1,3,7,11-tridecatetraene (TMTT) that is released by many plants in response to herbivory and may help to attract predators to combat the herbivores
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-
?
geranylgeranyl diphosphate + H2O
(E,E)-geranyllinalool + diphosphate
no activity with geranyl diphosphate or farnesyl diphosphate
-
-
?
geranylgeranyl diphosphate + H2O
(E,E)-geranyllinalool + diphosphate
the product (E,E)-geranyllinalool is a precursor to the volatile compound 4,8,12-trimethyl-1,3,7,11-tridecatetraene (TMTT) that is released by many plants in response to herbivory and may help to attract predators to combat the herbivores
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-
?
geranylgeranyl diphosphate + H2O
(E,E)-geranyllinalool + diphosphate
no activity with geranyl diphosphate or farnesyl diphosphate
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-
?
geranylgeranyl diphosphate + H2O
(E,E)-geranyllinalool + diphosphate
KJ755868
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-
-
?
geranylgeranyl diphosphate + H2O
(E,E)-geranyllinalool + diphosphate
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additional products are + linalool + (E)-nerolidol. Products are precursors of (E,E)-4,8,12-trimethyltrideca-1,3,7,11-tetraene
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?
geranylgeranyl diphosphate + H2O
(E,E)-geranyllinalool + diphosphate
KJ755870
enzyme is 55fold more efficient with geranylgeranyl diphosphate than with farnesyl diphosphate. Reaction with farnesyl diphosphate yields nerolidol
single major product
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?
additional information
?
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the partially purified LnTPS3 protein catalyzes the formation of geranyllinalool from geranylgeranyl diphosphate (GGPP) and trans-nerolidol from eeFPP, GC-MS analysis of reaction products. In absence of functional LnTPS3, no trans-geranyllinalool and trans-nerolidol synthase activities are detected. No activity with geranyl diphosphate
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-
?
additional information
?
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the partially purified LnTPS3 protein catalyzes the formation of geranyllinalool from geranylgeranyl diphosphate (GGPP) and trans-nerolidol from eeFPP, GC-MS analysis of reaction products. In absence of functional LnTPS3, no trans-geranyllinalool and trans-nerolidol synthase activities are detected. No activity with geranyl diphosphate
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-
?
additional information
?
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enzyme NaGLS is not active with geranyl diphosphate and farnesyl diphosphate, GC-MS analysis of compounds
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?
additional information
?
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enzyme NaGLS is not active with geranyl diphosphate and farnesyl diphosphate, GC-MS analysis of compounds
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-
?
additional information
?
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enzyme SlTPS46 shows no activity with geranyl diphospate, GC-MS analysis of compounds
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?
additional information
?
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enzyme SlTPS46 shows no activity with geranyl diphospate, GC-MS analysis of compounds
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-
?
