4.2.1.B6: (11Z)-etheroleic acid synthase

This is an abbreviated version!
For detailed information about (11Z)-etheroleic acid synthase, go to the full flat file.

Reaction

2 (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate =

Synonyms

CYP74M1, SmDES1

ECTree

     4 Lyases

         4.2 Carbon-oxygen lyases

             4.2.1 Hydro-lyases

                4.2.1.B6 (11Z)-etheroleic acid synthase

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Results	in table
1	AA Sequence
1	Cloned(Commentary)
2	kcat/KM [mM/s]
2	KM Value [mM]
6	Natural Substrates/ Products (Substrates)
4	Organism
1	pH Optimum
4	Reaction
4	Reference
3	Source Tissue
14	Substrates and Products (Substrate)
2	Synonyms
1	Systematic Name
1	Temperature Optimum [°C]
2	Turnover Number [1/s]

Natural Substrates Products

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Natural Substrates Products on EC 4.2.1.B6 - (11Z)-etheroleic acid synthase

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NATURAL SUBSTRATE

NATURAL PRODUCT

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

REVERSIBILITY
r=reversible
ir=irreversible
?=not specified

(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate

(9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O

2 entries

(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid

(9Z,11E)-12[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O

Selaginella moellendorffii

D8S724

i.e. 13-HPOD

747182

-

-

?

(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate

(9Z,11Z)-12-[(1E,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O

2 entries

(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoic acid

(9Z,11E)-12[(1Z,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O

Selaginella moellendorffii

D8S724

i.e. 13-HPOT

747182

-

-

?

(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate

(9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O

Ranunculus lingua

-

a two-step pathway involving 13-lipoxygenase and divinyl ether synthase is responsible for biosynthesis of divinyl ethers in the plant

705459

(9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid (i.e. omega5(Z)-etheroleic acid) and (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid (11Z-etheroleic acid)

-

?

(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate

(9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O

Ranunculus peltatus

-

a two-step pathway involving 13-lipoxygenase and divinyl ether synthase is responsible for biosynthesis of divinyl ethers in the plant

705459

(9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid (i.e. omega5(Z)-etheroleic acid) and (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid (11Z-etheroleic acid)

-

?

(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate

(9Z,11Z)-12-[(1E,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O

Ranunculus lingua

-

-

705459

i.e. (11Z)-etherolenic acid

-

?

(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate

(9Z,11Z)-12-[(1E,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O

Ranunculus peltatus

-

-

705459

i.e. (11Z)-etherolenic acid

-

?