4.2.1.B6: (11Z)-etheroleic acid synthase

This is an abbreviated version!
For detailed information about (11Z)-etheroleic acid synthase, go to the full flat file.

Reaction

2 (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate =

(9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid

(9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid

+ 2 H2O

Synonyms

CYP74M1, SmDES1

ECTree

4 Lyases

4.2 Carbon-oxygen lyases

4.2.1 Hydro-lyases

4.2.1.B6 (11Z)-etheroleic acid synthase

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Results	in table
1	AA Sequence
1	Cloned(Commentary)
2	kcat/KM [mM/s]
2	KM Value [mM]
6	Natural Substrates/ Products (Substrates)
4	Organism
1	pH Optimum
4	Reaction
4	Reference
3	Source Tissue
14	Substrates and Products (Substrate)
2	Synonyms
1	Systematic Name
1	Temperature Optimum [°C]
2	Turnover Number [1/s]

Reference

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Reference on EC 4.2.1.B6 - (11Z)-etheroleic acid synthase

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703621

Hamberg, M.

Hidden stereospecificity in the biosynthesis of divinyl ether fatty acids

FEBS J.

272

736-743

2005

Ranunculus lingua

15670154

705459

Hamberg, M.

Biosynthesis of new divinyl ether oxylipins in Ranunculus plants

Lipids

427-433

2002

Ranunculus lingua, Ranunculus peltatus

12030324

747182

Gorina, S.S.; Toporkova, Y.Y.; Mukhtarova, L.S.; Smirnova, E.O.; Chechetkin, I.R.; Khairutdinov, B.I.; Gogolev, Y.V.; Grechkin, A.N.

Oxylipin biosynthesis in spikemoss Selaginella moellendorffii molecular cloning and identification of divinyl ether synthases CYP74M1and CYP74M3

Biochim. Biophys. Acta

1861

301-309

2016

Selaginella moellendorffii (D8S724), Selaginella moellendorffii

26776054