4.2.1.169: 3-vinyl bacteriochlorophyllide d 31-hydratase
This is an abbreviated version!
For detailed information about 3-vinyl bacteriochlorophyllide d 31-hydratase, go to the full flat file.
Reaction
Synonyms
3-vinyl hydratase, bacterial 3-vinyl hydratase, bacteriochlorophyll c3(1) hydratase, bchF, BchV, C3-vinyl hydratase, chV, CT1776
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Natural Substrates Products
Natural Substrates Products on EC 4.2.1.169 - 3-vinyl bacteriochlorophyllide d 31-hydratase
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REACTION DIAGRAM
3-deacetyl-3-vinyl-bacteriochlorophyllide a + H2O
3-deacetyl-3-(1-hydroxyethyl)-bacteriochlorophyllide a
3-vinyl bacteriochlorophyllide d + H2O
(3RS)-3-(1-hydroxyethyl) bacteriochlorophyllide d
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high activity, the enzyme converts [E,M], [E,E], [P,E], and [E,I] variants, the [E,E] and [P,E] variants are preferred substrates, stereochemistry, overview
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?
3-vinyl-8,12-diethyl-bacteriochlorophyllide d + H2O
(31R)-(1-hydroxyethyl)-8,12-diethyl-bacteriochlorophyllide d
3-vinyl-8-ethyl-12-methyl-bacteriochlorophyllide d + H2O
(31R)-(1-hydroxyethyl)-8-ethyl-12-methyl-bacteriochlorophyllide d
3-vinyl-8-isobutyl-12-ethyl-bacteriochlorophyllide d + H2O
(31RS)3-(1-hydroxyethyl) bacteriochlorophyllide d
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?
3-vinyl-8-propyl-12-ethyl-bacteriochlorophyllide d + H2O
(3RS)3-(1-hydroxyethyl)-8-propyl-12-ethyl-bacteriochlorophyllide d
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?
3-deacetyl-3-(1-hydroxyethyl)-bacteriochlorophyllide a
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?
3-deacetyl-3-vinyl-bacteriochlorophyllide a + H2O
3-deacetyl-3-(1-hydroxyethyl)-bacteriochlorophyllide a
Chlorobaculum tepidum ATCC 49652 / DSM 12025 / NBRC 103806 / TLS
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?
(31RS)-3-(1-hydroxyethyl) bacteriochlorophyllide a
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?
3-vinyl bacteriochlorophyllide a + H2O
(31RS)-3-(1-hydroxyethyl) bacteriochlorophyllide a
Chlorobaculum tepidum ATCC 49652 / DSM 12025 / NBRC 103806 / TLS
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?
(31S)-3-(1-hydroxyethyl) bacteriochlorophyllide c
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low activity
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?
3-vinyl bacteriochlorophyllide c + H2O
(31S)-3-(1-hydroxyethyl) bacteriochlorophyllide c
Chlorobaculum tepidum ATCC 49652 / DSM 12025 / NBRC 103806 / TLS
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low activity
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?
(31R)-(1-hydroxyethyl)-8,12-diethyl-bacteriochlorophyllide d
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?
3-vinyl-8,12-diethyl-bacteriochlorophyllide d + H2O
(31R)-(1-hydroxyethyl)-8,12-diethyl-bacteriochlorophyllide d
Chlorobaculum tepidum ATCC 49652 / DSM 12025 / NBRC 103806 / TLS
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?
(31R)-(1-hydroxyethyl)-8-ethyl-12-methyl-bacteriochlorophyllide d
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?
3-vinyl-8-ethyl-12-methyl-bacteriochlorophyllide d + H2O
(31R)-(1-hydroxyethyl)-8-ethyl-12-methyl-bacteriochlorophyllide d
Chlorobaculum tepidum ATCC 49652 / DSM 12025 / NBRC 103806 / TLS
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?
a 3-vinyl bacteriochlorophyllide d + H2O
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?
a 3-(1-hydroxyethyl) bacteriochlorophyllide d
a 3-vinyl bacteriochlorophyllide d + H2O
Chlorobaculum tepidum ATCC 49652 / DSM 12025 / NBRC 103806 / TLS
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?
a 3-(1-hydroxyethyl) bacteriochlorophyllide d
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?
a 3-vinyl bacteriochlorophyllide d + H2O
a 3-(1-hydroxyethyl) bacteriochlorophyllide d
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?
a 3-vinyl bacteriochlorophyllide d + H2O
a 3-(1-hydroxyethyl) bacteriochlorophyllide d
bacteriochlorophyllide d is converted to bacteriochlorophyllide c
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?
a 3-vinyl bacteriochlorophyllide d + H2O
a 3-(1-hydroxyethyl) bacteriochlorophyllide d
enzyme BchV prefers the S-stereoisomer, stereospecific reaction
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?
a 3-vinyl bacteriochlorophyllide d + H2O
a 3-(1-hydroxyethyl) bacteriochlorophyllide d
Chlorobaculum tepidum ATCC 49652
enzyme BchV prefers the S-stereoisomer, stereospecific reaction
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?
a 3-vinyl bacteriochlorophyllide d + H2O
a 3-(1-hydroxyethyl) bacteriochlorophyllide d
bacteriochlorophyllide d is converted to bacteriochlorophyllide c
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?
a 3-vinyl bacteriochlorophyllide d + H2O
a 3-(1-hydroxyethyl) bacteriochlorophyllide d
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?
3-devinyl-3-(1-hydroxyethyl)-chlorophyllide a
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?
chlorophyllide a + H2O
3-devinyl-3-(1-hydroxyethyl)-chlorophyllide a
cf. EC 4.2.1.165
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chlorophyllide a + H2O
3-devinyl-3-(1-hydroxyethyl)-chlorophyllide a
Chlorobaculum tepidum ATCC 49652 / DSM 12025 / NBRC 103806 / TLS
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?
chlorophyllide a + H2O
3-devinyl-3-(1-hydroxyethyl)-chlorophyllide a
cf. EC 4.2.1.165
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the enzyme is a bacteriochlorophyllide c-specific BchF paralogue, cf. EC 4.2.1.165. BchV catalyzes the hydration of the C-3 vinyl group of highly methylated bacteriochlorophyllide species to produce S-stereochemistry
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additional information
?
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the in vitro stereoselective hydration confirms the in vivo production of the S-epimeric species by BchV
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additional information
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the in vitro stereoselective hydration confirms the in vivo production of the S-epimeric species by BchV
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additional information
?
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the in vitro stereoselective hydration confirms the in vivo production of the S-epimeric species by BchV
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?
additional information
?
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Chlorobaculum tepidum ATCC 49652
the in vitro stereoselective hydration confirms the in vivo production of the S-epimeric species by BchV
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?
additional information
?
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Chlorobaculum tepidum ATCC 49652
the in vitro stereoselective hydration confirms the in vivo production of the S-epimeric species by BchV
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-
?
additional information
?
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the enzyme is a bacteriochlorophyllide c-specific BchF paralogue, cf. EC 4.2.1.165. BchV catalyzes the hydration of the C-3 vinyl group of highly methylated bacteriochlorophyllide species to produce S-stereochemistry
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?