1.14.19.9: tryptophan 7-halogenase
This is an abbreviated version!
For detailed information about tryptophan 7-halogenase, go to the full flat file.
Word Map on EC 1.14.19.9
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1.14.19.9
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fadh2-dependent
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dichlorination
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halometabolites
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rebeccamycin
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alpha-ketoglutarate-dependent
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haloperoxidases
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syringomycin
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alphakg-dependent
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pyrrolnitrin
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alphakg
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l-thr
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organohalogens
- 1.14.19.9
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fadh2-dependent
-
dichlorination
-
halometabolites
- rebeccamycin
-
alpha-ketoglutarate-dependent
- haloperoxidases
-
syringomycin
-
alphakg-dependent
- pyrrolnitrin
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alphakg
- l-thr
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organohalogens
Reaction
Synonyms
EC 1.14.14.7, FAD-dependent halogenase, flavin-dependent halogenase, flavin-dependent tryptophan halogenase, halogenase, KtzQ, L-tryptophan-7-halogenase, PrnA, RebH, Trp 7-hal, Trp halogenase, Trp-7-Hal, Trp-7-halogenase
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Natural Substrates Products
Natural Substrates Products on EC 1.14.19.9 - tryptophan 7-halogenase
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REACTION DIAGRAM
6-chloro-L-tryptophan + FADH2 + chloride + O2 + H+
6,7-dichloro-L-tryptophan + FAD + 2 H2O
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?
L-tryptophan + FADH2 + Cl- + O2
7-chloro-L-tryptophan + FAD + H2O
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formation of 7-chlorotryptophan as the initial step in the biosynthesis of antitumor agent rebeccamycin
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-
?
tryptophan + FADH2 + chloride + O2 + H+
7-chloro-L-tryptophan + FAD + 2 H2O
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-
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?
tryptophan + FADH2 + Cl- + O2 + H+
7-chloro-L-tryptophan + FAD + 2 H2O
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-
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-
?
tryptophan + FADH2 + Cl- + O2 + H+
7-chloro-L-tryptophan + FAD + H2O
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-
-
?
tryptophan + FADH2 + O2 + Cl- + H+
7-chlorotryptophan + FAD + H2O
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initial step of rebeccamycin biosynthesis
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-
?
7-chloro-L-tryptophan + FAD + 2 H2O
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?
L-tryptophan + FADH2 + chloride + O2 + H+
7-chloro-L-tryptophan + FAD + 2 H2O
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-
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?
7-chloro-L-tryptophan + FAD + H2O
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the enzyme is involved in biosynthesis of pyrrolnitrin
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-
?
L-tryptophan + FADH2 + Cl- + O2 + H+
7-chloro-L-tryptophan + FAD + H2O
the enzyme is involved in biosynthesis of pyrrolnitrin
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-
?
7-chloro-tryptophan + FAD + H2O
rebeccamycin biosynthesis
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-
?
tryptophan + FADH2 + Cl- + O2 + H+
7-chloro-tryptophan + FAD + H2O
chlorination of its natural substrate tryptophan exclusively at the 7-position, a position at which direct chemical chlorination is not possible
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-
?
tryptophan + FADH2 + Cl- + O2 + H+
7-chloro-tryptophan + FAD + H2O
rebeccamycin biosynthesis
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-
?
tryptophan + FADH2 + Cl- + O2 + H+
7-chloro-tryptophan + FAD + H2O
chlorination of its natural substrate tryptophan exclusively at the 7-position, a position at which direct chemical chlorination is not possible
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?
?
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first step in biosynthesis of rebeccamycin
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additional information
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first step in pyrrolnitrin biosynthetic pathway
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?