EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.14.148 | (+)-columbianetin + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Peucedanum praeruptorum |
angelicin + acetone + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |
1.14.14.148 | (+)-columbianetin + [reduced NADPH-hemoprotein reductase] + O2 |
the enzyme is involved in angular furanocoumarin pathway |
Pastinaca sativa |
angelicin + acetone + [oxidized NADPH-hemoprotein reductase] + H2O |
negligible amounts of a hydroxylated columbianetin by-product |
? |
1.14.14.148 | (+)-columbianetin + [reduced NADPH-hemoprotein reductase] + O2 |
angelicin synthase attacks columbianetin by syn-elimination of hydrogen from C-3' |
Pastinaca sativa |
angelicin + acetone + [oxidized NADPH-hemoprotein reductase] + H2O |
negligible amounts of a hydroxylated columbianetin by-product |
? |
1.14.14.148 | syn-[3'D]columbianetin + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Pastinaca sativa |
syn-[3'D](anti-3'-hydroxy)-columbianetin + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |