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Results 1 - 10 of 48 > >>
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EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the word mapDisplay the reaction diagram Show all sequences 1.1.1.311more the enzyme is used for chemoenzymatic synthesis of enantiomerically enriched (S)- and (R)-gamma-aryl-gamma-butyrolactones, whereby the key step is an enzyme-catalyzed stereoselective reduction of methyl 4-oxo-4-arylbutanoates, (S)-PED-catalyzed bioreduction Aromatoleum aromaticum ? - -
Display the word mapDisplay the reaction diagram Show all sequences 1.1.1.311more the low pH cluster model is used to investigate kinetics and thermodynamics of the PEDH catalysed reductions of ketones to alcohols. The optimization of enzyme-ketone complexes (ES), transitions states (TS) as well as the enzyme-alcohol complexes (EP) are obtained for acetophenone and its structural analogues: 2,2-di-chloroacetophenone, 2-chloroacetophenone, 4'-nitroacetophenone, 4'-hydroxyacetophenone, 4'-methoxyacetophenone, 4'-ethylacetophenone, 4'-fluoroacetophenone, 4'-chloroacetophenone, 4'-bromoacetophenone, and 2-acetyl- and 4-acetylpyridine. Analysis of transition states for acetophenone derivatives, kinetic and thermodynamic analysis, overview Aromatoleum aromaticum ? - -
Display the word mapDisplay the reaction diagram Show all sequences 1.1.1.311more the enzyme is used for chemoenzymatic synthesis of enantiomerically enriched (S)- and (R)-gamma-aryl-gamma-butyrolactones, whereby the key step is an enzyme-catalyzed stereoselective reduction of methyl 4-oxo-4-arylbutanoates, (S)-PED-catalyzed bioreduction Aromatoleum aromaticum EbN1 ? - -
Display the word mapDisplay the reaction diagram Show all sequences 1.1.1.311more the low pH cluster model is used to investigate kinetics and thermodynamics of the PEDH catalysed reductions of ketones to alcohols. The optimization of enzyme-ketone complexes (ES), transitions states (TS) as well as the enzyme-alcohol complexes (EP) are obtained for acetophenone and its structural analogues: 2,2-di-chloroacetophenone, 2-chloroacetophenone, 4'-nitroacetophenone, 4'-hydroxyacetophenone, 4'-methoxyacetophenone, 4'-ethylacetophenone, 4'-fluoroacetophenone, 4'-chloroacetophenone, 4'-bromoacetophenone, and 2-acetyl- and 4-acetylpyridine. Analysis of transition states for acetophenone derivatives, kinetic and thermodynamic analysis, overview Aromatoleum aromaticum EbN1 ? - -
Display the word mapDisplay the reaction diagram Show all sequences 1.1.1.3112,2,2-trifluoroacetophenone + NADH + H+ - Aromatoleum aromaticum (S)-1-phenyl-2,2,2-trifluoroethan-1-ol + NAD+ 100% enantiomertic excess ?
Display the word mapDisplay the reaction diagram Show all sequences 1.1.1.3112,2,2-trifluoroacetophenone + NADH + H+ - Aromatoleum aromaticum EbN1 (S)-1-phenyl-2,2,2-trifluoroethan-1-ol + NAD+ 100% enantiomertic excess ?
Display the word mapDisplay the reaction diagram Show all sequences 1.1.1.3112,4'-dichloroacetophenone + NADH + H+ - Aromatoleum aromaticum (S)-2-chloro-1-(4-chloro-phenyl)-ethanol + NAD+ 100% enantiomeric excess ?
Display the word mapDisplay the reaction diagram Show all sequences 1.1.1.3112,4'-dichloroacetophenone + NADH + H+ - Aromatoleum aromaticum EbN1 (S)-2-chloro-1-(4-chloro-phenyl)-ethanol + NAD+ 100% enantiomeric excess ?
Display the word mapDisplay the reaction diagram Show all sequences 1.1.1.3114'-hydroxyacetophenone + NADH + H+ - Aromatoleum aromaticum (S)-4-(1-hydroxyethyl)phenol + NAD+ 90% enantiomeric excess ?
Display the word mapDisplay the reaction diagram Show all sequences 1.1.1.3114-acetylbiphenyl + NADH + H+ - Aromatoleum aromaticum (S)-1-(biphenyl-4-yl)ethanol + NAD+ 100% enantiomeric excess ?
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