EC Number   |
Substrates |
Organism |
Products |
Reversibility |
|---|
   1.14.13.92 | rac-2-ethylcyclohexanone + NADPH + O2 |
substrate is only accepted by mutants of phenylacetone monooxygenase, reaction is performed in presence of 2 U secondary alcohol dehydrogenase from Thermoanaerobacter ethanolicus and isopropanol to recover NADPH |
Thermobifida fusca |
benzyl acetate + NADP+ + H2O |
- |
? |
| 1.14.13.92 | rac-3-methyl-4-phenylbutan-2-one + NADH + H+ + O2 |
enantioselective reaction by PAMO |
Thermobifida fusca |
(2R)-1-phenylpropan-2-yl acetate + NAD+ + H2O |
- |
? |
| 1.14.13.92 | rac-3-methyl-4-phenylbutan-2-one + NADPH + H+ + O2 |
enantioselective reaction by PAMO |
Thermobifida fusca |
(2R)-1-phenylpropan-2-yl acetate + NADP+ + H2O |
- |
? |
| 1.14.13.92 | rac-bicyclo [3.2.0]hept-2-en-6-one + NADPH + O2 |
activity and stereoselectivity of wild-type and mutant enzymes, overview |
Thermobifida fusca |
? |
- |
? |
| 1.14.13.92 | thioanisole + NADH + H+ + O2 |
low activity, less enantioselective reaction |
Thermobifida fusca |
thioanisole sulfoxide + NAD+ + H2O |
- |
? |
| 1.14.13.92 | thioanisole + NADPH + H+ + O2 |
- |
Thermobifida fusca |
methyl phenyl sulfoxide + NADP+ + H2O |
- |
? |
| 1.14.13.92 | thioanisole + NADPH + H+ + O2 |
- |
Thermobifida fusca |
? |
- |
? |
| 1.14.13.92 | thioanisole + NADPH + H+ + O2 |
the asymmetric oxidation of thioanisole to sulfoxide is accompanied by the overoxidation to achiral sulfone |
Thermobifida fusca |
? |
- |
? |
| 1.14.13.92 | thioanisole + NADPH + H+ + O2 |
enantioselective reaction |
Thermobifida fusca |
thioanisole sulfoxide + NADP+ + H2O |
mainly (R)-sulfoxide |
? |
