4.2.3.150 | geranylgeranyl diphosphate = (R)-cembrene A + diphosphate |
the cyclization mechanism from geranylgeranyl diphosphate to cembrene A requires a 1,14-cyclization to the ent-cembranyl cation and deprotonation of one of the geminal methyl groups, reaction mechanism, overview |
-, 746752 |