EC Number |
Natural Substrates |
---|
4.2.1.B8 | (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate |
- |
4.2.1.B8 | (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid |
- |
4.2.1.B8 | (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid |
i.e. 13-HPOD |
4.2.1.B8 | (9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate |
highly preferred substrate |
4.2.1.B8 | (9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoic acid |
i.e. 13-HPOT |
4.2.1.B8 | more |
preferred substrates of the enzyme are the 13-hydroperoxides of alpha-linolenic and linoleic acids, which are converted to the divinyl ether oxylipins (omega5Z)-etherolenic acid, (9Z,11E)-12-[(1?Z,3?Z)-hexadienyloxy]-9,11-dodecadienoic acid, and (omega5Z)-etheroleic acid, (9Z,11E)-12-[(1?Z)-hexenyloxy]-9,11-dodecadienoic acid, respectively, as revealed by the data of mass spectrometry, NMR and UV spectroscopy |