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1.1.1.80
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replacement of the zinc from Thermoanaerobacter brockii alcohol dehydrogenase (TbADH) with Rh(III) catalysts possessing nitrogen donor ligands, by covalent conjugation to the active site cysteine, to create artificial metalloenzymes for NADP+ reduction. Compatibility between bioconjugated Rh catalysts and TbADH, overview. Formate dehydrogenase activity of artificial brominated metalloenzymes is observed
760881
1.1.1.80
Zn2+
required, analysis of the zion ion bound in the crystal structure of TbADH complexed to NADP+ (PDB ID 1YKF)
760881
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