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Literature summary extracted from
- Four-electron oxidation of p-hydroxylaminobenzoate to p-nitrobenzoate by a peroxodiferric complex in AurF from Streptomyces thioluteus (2010), Proc. Natl. Acad. Sci. USA, 107, 15722-15727 .
Organism
| EC Number | Organism | UniProt | Comment | Textmining |
|---|---|---|---|---|
| 1.14.99.68 | Streptomyces thioluteus | Q70KH9 | - |
- |
Substrates and Products (Substrate)
| EC Number | Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|---|
| 1.14.99.68 | 4-aminobenzoate + reduced acceptor + 2 O2 | - |
Streptomyces thioluteus | 4-nitrobenzoate + acceptor + 2 H2O | - |
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General Information
| EC Number | General Information | Comment | Organism |
|---|---|---|---|
| 1.14.99.68 | physiological function | peroxo-Fe2 III-III AurF oxidizes 4-hydroxylaminobenzoate Ar-NHOH. This reaction proceeds through to the Ar-NO2 final product, a four-electron oxidation, and produces Fe2 II-II AurF, with which O2 can combine to regenerate peroxo-Fe2 III-III AurF. Conversion of Ar-NHOH to Ar-NO2 requires only a single equivalent of O2 is fully catalytic in the absence of exogenous reducing equivalents | Streptomyces thioluteus |
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