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Literature summary extracted from

  • Chuang, L.; Wen, C.H.; Lee, Y.R.; Lin, Y.L.; Hsu, L.R.; Wang, S.Y.; Chu, F.H.
    Identification, functional characterization, and seasonal expression patterns of five sesquiterpene synthases in Liquidambar formosana (2018), J. Nat. Prod., 81, 1162-1172 .
    View publication on PubMed

Cloned(Commentary)

EC Number Cloned (Comment) Organism
4.2.3.198 expression in Escherichia coli strain BL21 Liquidambar formosana

Molecular Weight [Da]

EC Number Molecular Weight [Da] Molecular Weight Maximum [Da] Comment Organism
4.2.3.198 64488
-
 calculated from sequence Liquidambar formosana

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
4.2.3.57 (2E,6E)-farnesyl diphosphate Liquidambar formosana
-
 (trans)-beta-caryophyllene + diphosphate
-
 ?
4.2.3.133 2 (2E,6E)-farnesyl diphosphate Liquidambar formosana
-
 (-)-alpha-copaene + delta-cadinene + 2 diphosphate
-
 ?
4.2.3.198 (2E,6E)-farnesyl diphosphate Liquidambar formosana
-
 alpha-selinene + diphosphate
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
4.2.3.57 Liquidambar formosana
-
 Formosan sweet gum
-
4.2.3.133 Liquidambar formosana
-
 Formosan sweet gum
-
4.2.3.198 Liquidambar formosana
-
-
-

Source Tissue

EC Number Source Tissue Comment Organism Textmining
4.2.3.57 leaf
-
 Liquidambar formosana
-
4.2.3.133 leaf
-
 Liquidambar formosana
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.2.3.57 (2E,6E)-farnesyl diphosphate
-
 Liquidambar formosana (trans)-beta-caryophyllene + diphosphate
-
 ?
4.2.3.133 2 (2E,6E)-farnesyl diphosphate
-
 Liquidambar formosana (-)-alpha-copaene + delta-cadinene + 2 diphosphate
-
 ?
4.2.3.198 (2E,6E)-farnesyl diphosphate
-
 Liquidambar formosana alpha-selinene + diphosphate
-
 ?
4.2.3.198 (2E,6E)-farnesyl diphosphate alpha-selinene i.e. (2R,4aR,8aS)-4,8a-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene. The enzyme also produces traces of aromadendrene i.e. (1aR,4aR,7R,7aR,7bS)-1,1,7-trimethyl-4-methylidenedecahydro-1H-cyclopropa[e]azulene Liquidambar formosana alpha-selinene + diphosphate
-
 ?

Synonyms

EC Number Synonyms Comment Organism
4.2.3.57 TPS04
-
 Liquidambar formosana
4.2.3.133 TPS04
-
 Liquidambar formosana
4.2.3.198 LfTPS2
-
 Liquidambar formosana
4.2.3.198 TPS02
-
 Liquidambar formosana

pI Value

EC Number Organism Comment pI Value Maximum pI Value
4.2.3.198 Liquidambar formosana calculated from sequence
-
 5.2

Expression

EC Number Organism Comment Expression
4.2.3.133 Liquidambar formosana enzyme expression is induced by methyl jasmonate treatment up
4.2.3.198 Liquidambar formosana seasonal diversification, gene expression of Lf TPS02 is enhanced from the start of the growing season and declines after July down
4.2.3.198 Liquidambar formosana seasonal diversification, gene expression of Lf TPS02 is enhanced from the start of the growing season and declines after July up