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Literature summary extracted from

  • Gargouri, M.; Drouet, P.; Legoy, M.-D.
    Hydroperoxide-lyase activity in mint leaves volatile C6-aldehyde production from hydroperoxy-fatty acids (2004), J. Biotechnol., 111, 59-65 .
    View publication on PubMed

Localization

EC Number Localization Comment Organism GeneOntology No. Textmining
4.2.1.92 chloroplast membrane membrane-bound Mentha spicata 31969
-
4.2.1.92 chloroplast membrane membrane-bound Mentha pulegium 31969
-

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
4.2.1.92 (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid Mentha spicata
-
 hexanal + 12-oxo-9-dodecenoic acid
-
 ?
4.2.1.92 (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid Mentha pulegium
-
 hexanal + 12-oxo-9-dodecenoic acid
-
 ?
4.2.1.92 (9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoic acid Mentha spicata
-
 (Z)-3-hexenal + 12-oxo-9-dodecenoic acid
-
 ?
4.2.1.92 (9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoic acid Mentha pulegium
-
 (Z)-3-hexenal + 12-oxo-9-dodecenoic acid
-
 ?
4.2.1.92 additional information Mentha spicata the enzyme cleaves 13(S)-hydroperoxy-C18 fatty acids into C6-aldehyde and C12-oxo-acid ?
-
 ?
4.2.1.92 additional information Mentha pulegium the enzyme cleaves 13(S)-hydroperoxy-C18 fatty acids into C6-aldehyde and C12-oxo-acid ?
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
4.2.1.92 Mentha pulegium
-
-
-
4.2.1.92 Mentha spicata
-
-
-

Purification (Commentary)

EC Number Purification (Comment) Organism
4.2.1.92 solubilization of the enzyme from plant leaves by 1% Tween-20 Mentha spicata
4.2.1.92 solubilization of the enzyme from plant leaves by 1% Tween-20 Mentha pulegium

Source Tissue

EC Number Source Tissue Comment Organism Textmining
4.2.1.92 leaf
-
 Mentha spicata
-
4.2.1.92 leaf
-
 Mentha pulegium
-
4.2.1.92 stem upper parts Mentha spicata
-
4.2.1.92 stem upper parts Mentha pulegium
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.2.1.92 (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid
-
 Mentha spicata hexanal + 12-oxo-9-dodecenoic acid
-
 ?
4.2.1.92 (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid
-
 Mentha pulegium hexanal + 12-oxo-9-dodecenoic acid
-
 ?
4.2.1.92 (9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoic acid
-
 Mentha spicata (Z)-3-hexenal + 12-oxo-9-dodecenoic acid
-
 ?
4.2.1.92 (9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoic acid
-
 Mentha pulegium (Z)-3-hexenal + 12-oxo-9-dodecenoic acid
-
 ?
4.2.1.92 additional information the enzyme cleaves 13(S)-hydroperoxy-C18 fatty acids into C6-aldehyde and C12-oxo-acid Mentha spicata ?
-
 ?
4.2.1.92 additional information the enzyme cleaves 13(S)-hydroperoxy-C18 fatty acids into C6-aldehyde and C12-oxo-acid Mentha pulegium ?
-
 ?
4.2.1.92 additional information the enzyme cleaves 13(S)-hydroperoxy-C18 fatty acids into C6-aldehyde and C12-oxo-acid. GC-MS product analysis Mentha spicata ?
-
 ?
4.2.1.92 additional information the enzyme cleaves 13(S)-hydroperoxy-C18 fatty acids into C6-aldehyde and C12-oxo-acid. GC-MS product analysis Mentha pulegium ?
-
 ?

Synonyms

EC Number Synonyms Comment Organism
4.2.1.92 13-hydroperoxide-lyase
-
 Mentha spicata
4.2.1.92 13-hydroperoxide-lyase
-
 Mentha pulegium
4.2.1.92 HPL
-
 Mentha spicata
4.2.1.92 HPL
-
 Mentha pulegium
4.2.1.92 HPLS
-
 Mentha spicata
4.2.1.92 HPLS
-
 Mentha pulegium
4.2.1.92 hydroperoxide lyase
-
 Mentha spicata
4.2.1.92 hydroperoxide lyase
-
 Mentha pulegium

Temperature Optimum [°C]

EC Number Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
4.2.1.92 15
-
-
 Mentha spicata

pH Optimum

EC Number pH Optimum Minimum pH Optimum Maximum Comment Organism
4.2.1.92 7
-
-
 Mentha spicata