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Literature summary extracted from

  • Peter, S.; Karich, A.; Ullrich, R.; Groebe, G.; Scheibner, K.; Hofrichter, M.
    Enzymatic one-pot conversion of cyclohexane into cyclohexanone Comparison of four fungal peroxygenases (2014), J. Mol. Catal. B, 103, 47-51 .
No PubMed abstract available

KM Value [mM]

EC Number KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
1.11.2.1 0.397
-
 Cyclohexane at pH 7.0 and 22°C Coprinopsis cinerea
1.11.2.1 0.994
-
 Cyclohexane at pH 7.0 and 22°C Cyclocybe aegerita
1.11.2.1 1.844
-
 Cyclohexanol at pH 7.0 and 22°C Marasmius rotula
1.11.2.1 2.242
-
 Cyclohexane at pH 7.0 and 22°C Marasmius rotula
1.11.2.1 4.977
-
 Cyclohexanol at pH 7.0 and 22°C Cyclocybe aegerita
1.11.2.1 6.571
-
 Cyclohexanol at pH 7.0 and 22°C Coprinopsis cinerea

Organism

EC Number Organism UniProt Comment Textmining
1.11.2.1 Coprinopsis cinerea
-
-
-
1.11.2.1 Cyclocybe aegerita B9W4V6
-
-
1.11.2.1 Marasmius rotula
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.11.2.1 cyclohexane + H2O2
-
 Coprinopsis cinerea cyclohexanol + H2O
-
 ?
1.11.2.1 cyclohexane + H2O2
-
 Cyclocybe aegerita cyclohexanol + H2O
-
 ?
1.11.2.1 cyclohexane + H2O2
-
 Marasmius rotula cyclohexanol + H2O
-
 ?
1.11.2.1 cyclohexanol + H2O2
-
 Coprinopsis cinerea cyclohexanone + H2O
-
 ?
1.11.2.1 cyclohexanol + H2O2
-
 Cyclocybe aegerita cyclohexanone + H2O
-
 ?
1.11.2.1 cyclohexanol + H2O2
-
 Marasmius rotula cyclohexanone + H2O
-
 ?

Synonyms

EC Number Synonyms Comment Organism
1.11.2.1 UPO
-
 Coprinopsis cinerea
1.11.2.1 UPO
-
 Cyclocybe aegerita
1.11.2.1 UPO
-
 Marasmius rotula

Turnover Number [1/s]

EC Number Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
1.11.2.1 3
-
 Cyclohexanol at pH 7.0 and 22°C Coprinopsis cinerea
1.11.2.1 5
-
 Cyclohexanol at pH 7.0 and 22°C Cyclocybe aegerita
1.11.2.1 13
-
 Cyclohexane at pH 7.0 and 22°C Coprinopsis cinerea
1.11.2.1 31
-
 Cyclohexanol at pH 7.0 and 22°C Marasmius rotula
1.11.2.1 43
-
 Cyclohexane at pH 7.0 and 22°C Marasmius rotula
1.11.2.1 72
-
 Cyclohexane at pH 7.0 and 22°C Cyclocybe aegerita

Cofactor

EC Number Cofactor Comment Organism Structure
1.11.2.1 heme
-
 Coprinopsis cinerea
1.11.2.1 heme
-
 Cyclocybe aegerita
1.11.2.1 heme
-
 Marasmius rotula

kcat/KM [mM/s]

EC Number kcat/KM Value [1/mMs-1] kcat/KM Value Maximum [1/mMs-1] Substrate Comment Organism Structure
1.11.2.1 0.39
-
 Cyclohexanol at pH 7.0 and 22°C Coprinopsis cinerea
1.11.2.1 0.97
-
 Cyclohexanol at pH 7.0 and 22°C Cyclocybe aegerita
1.11.2.1 1.7
-
 Cyclohexanol at pH 7.0 and 22°C Marasmius rotula
1.11.2.1 3.2
-
 Cyclohexane at pH 7.0 and 22°C Coprinopsis cinerea
1.11.2.1 43
-
 Cyclohexane at pH 7.0 and 22°C Marasmius rotula
1.11.2.1 72
-
 Cyclohexane at pH 7.0 and 22°C Cyclocybe aegerita