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Literature summary extracted from

  • Oliw, E.H.; Cristea, M.; Hamberg, M.
    Biosynthesis and isomerization of 11-hydroperoxylinoleates by manganese- and iron-dependent lipoxygenases (2004), Lipids, 39, 319-323.
    View publication on PubMed

Organism

EC Number Organism UniProt Comment Textmining
1.13.11.45 Gaeumannomyces graminis
-
-
-

Reaction

EC Number Reaction Comment Organism Reaction ID
1.13.11.45 linoleate + O2 = (9Z,12Z)-(11S)-11-hydroperoxyoctadeca-9,12-dienoate mechanism via suprafacial migration of O2 Gaeumannomyces graminis

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.13.11.45 11-(11R)-hydroperoxy-(9Z,12Z)-octadecadienoic acid slow Gaeumannomyces graminis 9-(9R)-hydroperoxy-octadecadienoic acid
-
?
1.13.11.45 11-(11S)-hydroperoxy-(9Z,12Z)-octadecadienoic acid rapid Gaeumannomyces graminis 13-(13R)-hydroperoxy-(9Z,11E)-octadecadienoic acid
-
?
1.13.11.45 11-(11S)-hydroperoxy-(9Z,12Z)-octadecadienoic acid methyl ester
-
Gaeumannomyces graminis 13-(13R)-hydroperoxy-(9Z,11E)-octadecadienoic acid methyl ester
-
?