Any feedback?
Please rate this page
(literature.php)
(0/150)

BRENDA support

Literature summary extracted from

  • Krest, I.; Glodek, J.; Keusgen, M.
    Cysteine sulfoxides and alliinase activity of some Allium species (2000), J. Agric. Food Chem., 48, 3753-3760.
    View publication on PubMed

KM Value [mM]

EC Number KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
4.4.1.4 0.42
-
 (+)-S-(2-propenyl)-L-cysteine sulfoxide pH 7.0, 25°C Allium victorialis
4.4.1.4 0.47
-
 (+)-S-(2-propenyl)-L-cysteine sulfoxide pH 7.0, 25°C Allium saxatile
4.4.1.4 0.68
-
 (+)-S-(2-propenyl)-L-cysteine sulfoxide pH 7.0, 25°C Allium stipitatum
4.4.1.4 0.77
-
 (+)-S-(2-propenyl)-L-cysteine sulfoxide pH 7.0, 25°C Allium obliquum
4.4.1.4 0.85
-
 (+)-S-(2-propenyl)-L-cysteine sulfoxide pH 7.0, 25°C Allium subhirsutum
4.4.1.4 1.25
-
 (+)-S-(2-propenyl)-L-cysteine sulfoxide pH 7.0, 25°C Allium sativum
4.4.1.4 1.48
-
 (+)-S-(2-propenyl)-L-cysteine sulfoxide pH 7.0, 25°C Allium hymenorrhizum
4.4.1.4 1.59
-
 (+)-S-(2-propenyl)-L-cysteine sulfoxide pH 7.0, 25°C Allium sphaerocephalon
4.4.1.4 1.79
-
 (+)-S-(2-propenyl)-L-cysteine sulfoxide pH 7.0, 25°C Allium jesdianum

Natural Substrates/ Products (Substrates)

EC Number Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
4.4.1.4 additional information Allium sativum the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates ?
-
 ?
4.4.1.4 additional information Allium sphaerocephalon the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates ?
-
 ?
4.4.1.4 additional information Allium victorialis the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates ?
-
 ?
4.4.1.4 additional information Allium hymenorrhizum the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates ?
-
 ?
4.4.1.4 additional information Allium saxatile the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates ?
-
 ?
4.4.1.4 additional information Allium obliquum the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates ?
-
 ?
4.4.1.4 additional information Allium subhirsutum the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates ?
-
 ?
4.4.1.4 additional information Allium jesdianum the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates ?
-
 ?
4.4.1.4 additional information Allium stipitatum the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates ?
-
 ?

Organism

EC Number Organism UniProt Comment Textmining
4.4.1.4 Allium hymenorrhizum
-
-
-
4.4.1.4 Allium jesdianum
-
-
-
4.4.1.4 Allium obliquum
-
-
-
4.4.1.4 Allium sativum
-
-
-
4.4.1.4 Allium saxatile
-
-
-
4.4.1.4 Allium sphaerocephalon
-
-
-
4.4.1.4 Allium stipitatum
-
-
-
4.4.1.4 Allium subhirsutum
-
-
-
4.4.1.4 Allium victorialis
-
-
-

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.4.1.4 (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
 Allium sativum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
 Allium sphaerocephalon 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
 Allium victorialis 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
 Allium hymenorrhizum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
 Allium saxatile 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
 Allium obliquum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
 Allium subhirsutum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
 Allium jesdianum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (+)-S-(2-propenyl)-L-cysteine sulfoxide
-
 Allium stipitatum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (+/-)-(1-methyl)-L-cysteine sulfoxide about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium sphaerocephalon methanesulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(1-methyl)-L-cysteine sulfoxide about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium jesdianum methanesulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(1-methyl)-L-cysteine sulfoxide about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium sativum methanesulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(1-methyl)-L-cysteine sulfoxide about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium hymenorrhizum methanesulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(1-methyl)-L-cysteine sulfoxide about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium subhirsutum methanesulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(1-methyl)-L-cysteine sulfoxide about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium obliquum methanesulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(1-methyl)-L-cysteine sulfoxide about 35% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium saxatile methanesulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(1-methyl)-L-cysteine sulfoxide about 35% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium stipitatum methanesulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(1-methyl)-L-cysteine sulfoxide about 45% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium victorialis methanesulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(butyl)-L-cysteine sulfoxide 5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium subhirsutum butane-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(butyl)-L-cysteine sulfoxide 6.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium sativum butane-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(butyl)-L-cysteine sulfoxide 6.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium sphaerocephalon butane-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(butyl)-L-cysteine sulfoxide 6.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium victorialis butane-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(butyl)-L-cysteine sulfoxide 7% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium jesdianum butane-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(butyl)-L-cysteine sulfoxide 8% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium hymenorrhizum butane-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(butyl)-L-cysteine sulfoxide about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium saxatile butane-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(butyl)-L-cysteine sulfoxide about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium obliquum butane-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(butyl)-L-cysteine sulfoxide about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium stipitatum butane-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(propyl)-L-cysteine sulfoxide 3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium sativum propyl-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(propyl)-L-cysteine sulfoxide 3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium sphaerocephalon propyl-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(propyl)-L-cysteine sulfoxide 3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium victorialis propyl-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(propyl)-L-cysteine sulfoxide 4% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium hymenorrhizum propyl-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(propyl)-L-cysteine sulfoxide 7% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium subhirsutum propyl-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(propyl)-L-cysteine sulfoxide about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium stipitatum propyl-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(propyl)-L-cysteine sulfoxide about 20% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium jesdianum propyl-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(propyl)-L-cysteine sulfoxide about 5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium saxatile propyl-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (+/-)-(propyl)-L-cysteine sulfoxide about 5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium obliquum propyl-1-sulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 (-)-(2-propenyl)-L-cysteine sulfoxide about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium subhirsutum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (-)-(2-propenyl)-L-cysteine sulfoxide about 20% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium sativum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (-)-(2-propenyl)-L-cysteine sulfoxide about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium hymenorrhizum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (-)-(2-propenyl)-L-cysteine sulfoxide about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium obliquum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (-)-(2-propenyl)-L-cysteine sulfoxide about 3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium sphaerocephalon 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (-)-(2-propenyl)-L-cysteine sulfoxide about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium victorialis 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (-)-(2-propenyl)-L-cysteine sulfoxide about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium saxatile 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (-)-(2-propenyl)-L-cysteine sulfoxide about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium jesdianum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 (-)-(2-propenyl)-L-cysteine sulfoxide about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium stipitatum 2-propene-thioic acid + pyruvate + ammonia
-
 ?
4.4.1.4 additional information the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates Allium sativum ?
-
 ?
4.4.1.4 additional information the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates Allium sphaerocephalon ?
-
 ?
4.4.1.4 additional information the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates Allium victorialis ?
-
 ?
4.4.1.4 additional information the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates Allium hymenorrhizum ?
-
 ?
4.4.1.4 additional information the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates Allium saxatile ?
-
 ?
4.4.1.4 additional information the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates Allium obliquum ?
-
 ?
4.4.1.4 additional information the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates Allium subhirsutum ?
-
 ?
4.4.1.4 additional information the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates Allium jesdianum ?
-
 ?
4.4.1.4 additional information the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates Allium stipitatum ?
-
 ?
4.4.1.4 additional information no activity with (+/-)-(ethyl)-L-cysteine sulfoxide Allium jesdianum ?
-
 ?
4.4.1.4 S-ethyl-L-Cys sulfoxide + H2O about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium sativum ethylsulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 S-ethyl-L-Cys sulfoxide + H2O about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium sphaerocephalon ethylsulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 S-ethyl-L-Cys sulfoxide + H2O about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium subhirsutum ethylsulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 S-ethyl-L-Cys sulfoxide + H2O about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium hymenorrhizum ethylsulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 S-ethyl-L-Cys sulfoxide + H2O about 35% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium obliquum ethylsulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 S-ethyl-L-Cys sulfoxide + H2O about 50% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium saxatile ethylsulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 S-ethyl-L-Cys sulfoxide + H2O about 50% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium stipitatum ethylsulfenic acid + pyruvate + NH3
-
 ?
4.4.1.4 S-ethyl-L-Cys sulfoxide + H2O about 55% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide Allium victorialis ethylsulfenic acid + pyruvate + NH3
-
 ?

Temperature Optimum [°C]

EC Number Temperature Optimum [°C] Temperature Optimum Maximum [°C] Comment Organism
4.4.1.4 36
-
-
 Allium sphaerocephalon
4.4.1.4 36
-
-
 Allium hymenorrhizum
4.4.1.4 38
-
-
 Allium saxatile
4.4.1.4 38
-
-
 Allium obliquum
4.4.1.4 38
-
-
 Allium stipitatum
4.4.1.4 40
-
-
 Allium sativum
4.4.1.4 40
-
-
 Allium subhirsutum
4.4.1.4 44
-
-
 Allium victorialis
4.4.1.4 48
-
-
 Allium jesdianum

pH Optimum

EC Number pH Optimum Minimum pH Optimum Maximum Comment Organism
4.4.1.4 7
-
-
 Allium sativum
4.4.1.4 7
-
-
 Allium sphaerocephalon
4.4.1.4 7.5
-
-
 Allium victorialis
4.4.1.4 7.5
-
-
 Allium hymenorrhizum
4.4.1.4 7.5
-
-
 Allium saxatile
4.4.1.4 7.5
-
-
 Allium obliquum
4.4.1.4 7.5
-
-
 Allium subhirsutum
4.4.1.4 7.5
-
-
 Allium jesdianum
4.4.1.4 7.5
-
-
 Allium stipitatum

pH Range

EC Number pH Minimum pH Maximum Comment Organism
4.4.1.4 5.5 8.5 half-maximal activity at pH 5.5 and at pH 8.5 Allium sativum
4.4.1.4 5.5 8.5 half-maximal activity at pH 5.5 and at pH 8.5 Allium victorialis
4.4.1.4 5.5 8.5 half-maximal activity at pH 5.5 and at pH 8.5 Allium saxatile
4.4.1.4 5.5 8.5 half-maximal activity at pH 5.5 and at pH 8.5 Allium obliquum
4.4.1.4 5.5 8.5 half-maximal activity at pH 5.5 and at pH 8.5 Allium stipitatum
4.4.1.4 5.5 8 half-maximal activity at pH 5.5 and at pH 8.0 Allium sphaerocephalon
4.4.1.4 6 8.5 half-maximal activity at pH 6.0 and at pH 8.5 Allium hymenorrhizum
4.4.1.4 6.5 8.5 half-maximal activity at pH 6.5 and at pH 8.5 Allium subhirsutum
4.4.1.4 6.5 8.5 half-maximal activity at pH 6.5 and at pH 8.5 Allium jesdianum