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Literature summary extracted from

  • Schwab W.;Williams DC, Croteau R.
    Mechanism of monoterpene cyclization: stereochemistry of the transformation of noncyclizable substrate analogs by recombinant (-)-limonene synthase, (+)-bornyl diphosphate synthase, and (-)-pinene synthase (2002), J. Mol. Catal. B, 19, 415-421.
No PubMed abstract available

Cloned(Commentary)

EC Number Cloned (Comment) Organism
4.2.3.16 expressed in Escherichia coli Mentha spicata

Organism

EC Number Organism UniProt Comment Textmining
4.2.3.16 Mentha spicata
-
spearmint
-

Purification (Commentary)

EC Number Purification (Comment) Organism
4.2.3.16
-
Mentha spicata

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.2.3.16 6,7-dihydrogeranyl diphosphate
-
Mentha spicata ?
-
?
4.2.3.16 geranyl diphosphate cyclization proceeds via preliminary isomerization to the bound tertiary intermediate 3S-linalyl diphosphate Mentha spicata (-)-(4S)-limonene + diphosphate
-
?