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Literature summary extracted from

  • Carrea, G.; Redigolo, B.; Riva, S.; Colonna, S.; Gaggero, N.; Battistel, E.; Bianchi, D.
    Effects of substrate structure on the enantioselectivity and stereochemical course of sulfoxidation catalyzed by cyclohexanone monooxygenase (1992), Tetrahedron, 3, 1063-1068.
No PubMed abstract available

Organism

EC Number Organism UniProt Comment Textmining
1.14.13.22 Acinetobacter sp.
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 NCIB 9871
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Reaction

EC Number Reaction Comment Organism Reaction ID
1.14.13.22 cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O stereochemistry and enantioselectivity of the oxidation reaction depends strongly on the structure and stereochemistry of the substrates Acinetobacter sp.
a

Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1.14.13.22 cyclohexanone + NADPH + O2
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 Acinetobacter sp. 6-hexanolide + NADP+ + H2O
-
 ?
1.14.13.22 ethyl p-tolyl sulfide + NADPH + O2
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 Acinetobacter sp. (S)-ethyl p-tolyl sulfoxide + NADP+ + H2O
-
 ?
1.14.13.22 additional information active with diverse alkyl aryl sulfides, dialkyl sulfides and dialkyldisulfides Acinetobacter sp. ?
-
 ?
1.14.13.22 additional information high enantioselectivity in oxidation of sulfides Acinetobacter sp. ?
-
 ?