Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
---|---|---|---|---|---|---|
(E,E)-farnesyl diphosphate | Trichothecium roseum | - |
trichodiene + diphosphate | - |
? | |
(E,E)-farnesyl diphosphate | Fusarium sporotrichioides | - |
trichodiene + diphosphate | - |
? |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Fusarium sporotrichioides | - |
- |
- |
Trichothecium roseum | - |
- |
- |
Reaction | Comment | Organism | Reaction ID |
---|---|---|---|
(2E,6E)-farnesyl diphosphate = trichodiene + diphosphate | mechanism | Trichothecium roseum | |
(2E,6E)-farnesyl diphosphate = trichodiene + diphosphate | mechanism | Fusarium sporotrichioides |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
(3R)-nerolidyl diphosphate | - |
Trichothecium roseum | ? | - |
? | |
(3R)-nerolidyl diphosphate | - |
Fusarium sporotrichioides | ? | - |
? | |
(E,E)-farnesyl diphosphate | - |
Trichothecium roseum | trichodiene + diphosphate | - |
? | |
(E,E)-farnesyl diphosphate | - |
Fusarium sporotrichioides | trichodiene + diphosphate | - |
? | |
(E,E)-farnesyl diphosphate | formation of trichodiene involves initial generation of (3R)-nerolidyl diphosphate | Trichothecium roseum | trichodiene + diphosphate | - |
? | |
(E,E)-farnesyl diphosphate | formation of trichodiene involves initial generation of (3R)-nerolidyl diphosphate | Fusarium sporotrichioides | trichodiene + diphosphate | - |
? | |
(E,E)-farnesyl diphosphate | which cyclizes via the anti-boat conformation | Trichothecium roseum | trichodiene + diphosphate | - |
? | |
additional information | reaction proceeds via isomerization of farnesyl diphosphate to (3R)-nerolidyl diphosphate and further to trichodiene | Trichothecium roseum | ? | - |
? |