Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
---|---|---|---|---|---|---|
dimethylallyl diphosphate + L-tryptophan | Claviceps sp. | first pathway-specific enzyme of ergot alkaloid biosynthesis | diphosphate + L-4-(gamma,gamma-dimethylallyl)tryptophan | - |
? |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Claviceps sp. | - |
- |
- |
Reaction | Comment | Organism | Reaction ID |
---|---|---|---|
dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan | stereochemistry, direct attack of dimethylallyl diphosphate on C-4 of the indole | Claviceps sp. |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
dimethylallyl diphosphate + L-tryptophan | - |
Claviceps sp. | diphosphate + L-4-(gamma,gamma-dimethylallyl)tryptophan | - |
? | |
dimethylallyl diphosphate + L-tryptophan | first pathway-specific enzyme of ergot alkaloid biosynthesis | Claviceps sp. | diphosphate + L-4-(gamma,gamma-dimethylallyl)tryptophan | - |
? |