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IUBMB Comments Isolated from the hallucinogenic plant Salvia divinorum (seer’s sage) and the medicinal plant Tripterygium wilfordii (thunder god vine).
Synonyms
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clerodienyl diphosphate synthase
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-
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-
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geranylgeranyl diphosphate = (-)-kolavenyl diphosphate
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-
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-
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(-)-kolavenyl diphosphate lyase (ring-opening)
Isolated from the hallucinogenic plant Salvia divinorum (seer's sage) and the medicinal plant Tripterygium wilfordii (thunder god vine).
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geranylgeranyl diphosphate
(-)-kolavenyl diphosphate
Substrates: -
?
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geranylgeranyl diphosphate
(-)-kolavenyl diphosphate
Substrates: -
?
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0.0019
geranylgeranyl diphosphate
pH 7.0, 30°C
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0.88
geranylgeranyl diphosphate
pH 7.0, 30°C
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470
geranylgeranyl diphosphate
pH 7.0, 30°C
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UniProt
brenda
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peltate glandular trichome at abaxial surface and vein
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peltate glandular trichome at abaxial surface
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Highest Expressing Human Cell Lines
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Cell Line Links
Gene Links
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physiological function
enzyme catalyzes the first step of salvinorin A biosynthesis in Salvia divinorum. Transient expression in leaves of Nicotiana benthamiana leads to accumulation of (-)-kolavenol
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KPS_SALDI
787
0
89377
Swiss-Prot
-
TPS10_TRIWF
815
0
93441
Swiss-Prot
other Location (Reliability: 4 )
TPS28_TRIWF
815
0
93996
Swiss-Prot
other Location (Reliability: 2 )
TPS14_TRIWF
815
0
93935
Swiss-Prot
-
A0A0M3TC67_TRIWF
807
0
93537
TrEMBL
-
A0A0M4MZ71_TRIWF
815
0
94023
TrEMBL
other Location (Reliability: 1 )
A0A1B0YKB9_TRIWF
816
0
94180
TrEMBL
Secretory Pathway (Reliability: 1 )
A0A1C7AAN3_TRIWF
807
0
93529
TrEMBL
-
A0A222FXZ0_9ROSI
816
0
94259
TrEMBL
-
A0A222FX34_9ROSI
807
0
93540
TrEMBL
-
A0A288VHZ8_TRIWF
806
0
93391
TrEMBL
Secretory Pathway (Reliability: 1 )
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A314V
mutation does not change the product outcome
A314V/F255H
mutation leads to the recovery of the ability to produce (-)-kolavenyl diphosphate of wild-type while retaining the acquired function of forming ent-copalyl diphosphate of mutant F255H
F255H
mutation in direction to copalyl diphosphate synthase, mutant shows a complete switch of product specificity from (-)-kolavenyl diphosphate to ent-copalyl diphosphate
V200I
mutation does not change the product outcome
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Chen, X.; Berim, A.; Dayan, F.E.; Gang, D.R.
A (-)-kolavenyl diphosphate synthase catalyzes the first step of salvinorin A biosynthesis in Salvia divinorum
J. Exp. Bot.
68
1109-1122
2017
Salvia divinorum (A0A1S5RW73), Salvia divinorum
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