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Information on EC 5.4.4.4 - geraniol isomerase

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EC Tree
     5 Isomerases
         5.4 Intramolecular transferases
             5.4.4 Transferring hydroxy groups
                5.4.4.4 geraniol isomerase
IUBMB Comments
In absence of oxygen the bifunctional linalool dehydratase-isomerase can catalyse in vitro two reactions, the isomerization of (3S)-linalool to geraniol and the hydration of myrcene to (3S)-linalool, the latter activity being classified as EC 4.2.1.127, linalool dehydratase.
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The expected taxonomic range for this enzyme is: Castellaniella defragrans
Reaction Schemes
REACTION
REACTION DIAGRAM
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UNIPROT
LITERATURE
geraniol = (3S)-linalool
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